Homework Answers
7) option D is correct
Explanation: Reaction of alcohol with TsCl, pyridine produces tosylate as product. Reaction of tosylate with NaOH produces more substituted alkene as product. Hydroboration-oxidation of alkene with BH3, THF and H2O2, NaOH, H2O produces least substituted alcohol as product.
8) option D is correct
Explanation: NaNH2 is a strong base which gives dehydrohalogenation and produces acetylide ion as product.
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С. D. Which of the following sequences of reagents will be used to do the following transformation? он Он А. 1. KOt...
25) What reagents can best be used to accomplish the following transformation? A) H+, H2O B)1....
25) What reagents can best be used to accomplish the following transformation? A) H+, H2O B)1. BH3-THF 2. Ho, H202 C)1. Hg(OAc)2, H2O/THF 2. NaBH4 D)1. Hg(O2CCF3)2 CH3OH 2. NaBH4 E) NaOH, H20
Predict the major product(s) of the following reactions. Show stereochemistry where appropriate. (i) -COH На (i)...
Predict the major product(s) of the following reactions. Show stereochemistry where appropriate. (i) -COH На (i) Pd/C OsO4 NaHSO3, H20 н СHC1, КОН (iv) i) ВН, THF CECH in) H,О, NaOH Li, NH3 (liquid) (vi) XX H/H20 (vii) Two Markovnikov products Draw the structure of alkene for each of the following reactions. он BH3, THF i)H202 NaOH он )Hg(OAc)2 H20 i)NaBH (iii CH O i) Zn/H +
он Choose from the following list of reagents: H2, Lindlar's catalyst PCC, CH2Cl2 1) Br2 2)...
он Choose from the following list of reagents: H2, Lindlar's catalyst PCC, CH2Cl2 1) Br2 2) xs NaNH2 3) H20 1) NaNH2 2) H20 1) BH3 THF 2) H202, NaOH 9 H2CrO4 1) Hg(OAc)2, H20 dilute H2S04 H202, NaOH MCPBA 2) NaBH4 Enter the correct letter for each step of the reaction in the boxes below. (Reagents cannot be used more than once.) Step A: Step B:
Testbank, Question 015 Select the best reagents for the reaction below. + enantiomer OH 1) OsO4;...
Testbank, Question 015 Select the best reagents for the reaction below. + enantiomer OH 1) OsO4; 2) NaHSO3, H20 1) Hg(OAC)2, H20; 2) NaBH4 1) RCOZH; 2) H30+ 1) BH3-THF; 2) H2O2, NaOH 1) 03; 2) DMS
3. Complete the following reactions of the compound shown by drawing the correct products with CORRECT...
3. Complete the following reactions of the compound shown by drawing the correct products with CORRECT stereochemistry if important (10 pts). Br Br2 in H2O 1. O3 2. MegS HO H2/Pd OP A01018 1. Hg(OAc)2 in THF/Water 2. NaBH NaOH 1. BH3-THF 2. H2O2, NaOH estolqind, ( ym peroxyacid he anolbe o s HBr HBr/peroxide 1. OsO4 2. NAHSO3
10. Provide the reagents necessary to complete the following transformation. 13. Provide the structure of the...
10.
Provide the reagents necessary to complete the following
transformation. 13. Provide the structure of the major organic
product of the reaction below
10. Provide the reagents necessary to complete the following transformation. A. 1. BH3 THF 2. H202, HO B). H20, H2SO4 C. OsO4. H202 D. CH3CO3H E. 1. CH3CO3H 2. H, H20 11. Which of the following is the best reaction sequence to use if one wants to accomplish a Markovnikov addition of water to an alkene with...
Jos ou 2POMU PGJOM Which reagents are most likely to accomplish the reaction shown below? 4....
Jos ou 2POMU PGJOM Which reagents are most likely to accomplish the reaction shown below? 4. ОН 1. BH, THF / 2. HO", H2O2, H2O H, H20 1. Hg(OAc)2, H2O, THF / 2. NaBH 1. Hg(OAc)2, CH3OH / 2. NaBHA NaOH, H20
What is the correct sequence of reactions that can achieve the following multistep transformation? List in...
What is the correct sequence of reactions that can achieve the
following multistep transformation?
List in the correct order. (No spaces nor commas in between
letters) eg: GAKJO
☺ > REAGENTS A Br2 B TosCl, pyr CHOH SO, cat DO Na 1 MeBr 2. EtBr 3. NaNH 1 eq E 1. OsO4 2. NaHSO3 F NaNHExcess GHO H NBS, hv I HBr ROOR L HBr M NaOtBu N NaOEt O NaoMe PETOH, H+ Cat Q NaCN RH, Lindlar's SH, Pt...
Practice Problem 11.15a Identify reagents that can be used for the following synthesis: Draw the structure...
Practice Problem 11.15a
Identify reagents that can be used for the following
synthesis:
Draw the structure of compound A.
Practice Problem 11.15a Identify reagents that can be used for the following synthesis: он Compound A он correct. Identify reagent(s) that can be used to convert the starting alcohol into compound A. (1) TsCI, py; (2) NaOMe H2, Pt H2504 (1) TSCl, py; (2) t-BuOk SHOW ANSWER X Incorrect. Draw the structure of compound A 2 Edit Correct Identify reagent(s) that...
NaNH Br liq. NH 1) BH3, THF 2) H202, NaOH 1)Hg (OAC)2 B 2, THF-H2O 2)...
NaNH Br liq. NH 1) BH3, THF 2) H202, NaOH 1)Hg (OAC)2 B 2, THF-H2O 2) NaBH B SOCI Structure A Structure B
25) What reagents can best be used to accomplish the following transformation? A) H+, H2O B)1. BH3-THF 2. Ho, H202 C)1. Hg(OAc)2, H2O/THF 2. NaBH4 D)1. Hg(O2CCF3)2 CH3OH 2. NaBH4 E) NaOH, H20
Predict the major product(s) of the following reactions. Show stereochemistry where appropriate. (i) -COH На (i) Pd/C OsO4 NaHSO3, H20 н СHC1, КОН (iv) i) ВН, THF CECH in) H,О, NaOH Li, NH3 (liquid) (vi) XX H/H20 (vii) Two Markovnikov products Draw the structure of alkene for each of the following reactions. он BH3, THF i)H202 NaOH он )Hg(OAc)2 H20 i)NaBH (iii CH O i) Zn/H +
он Choose from the following list of reagents: H2, Lindlar's catalyst PCC, CH2Cl2 1) Br2 2) xs NaNH2 3) H20 1) NaNH2 2) H20 1) BH3 THF 2) H202, NaOH 9 H2CrO4 1) Hg(OAc)2, H20 dilute H2S04 H202, NaOH MCPBA 2) NaBH4 Enter the correct letter for each step of the reaction in the boxes below. (Reagents cannot be used more than once.) Step A: Step B:
Testbank, Question 015 Select the best reagents for the reaction below. + enantiomer OH 1) OsO4; 2) NaHSO3, H20 1) Hg(OAC)2, H20; 2) NaBH4 1) RCOZH; 2) H30+ 1) BH3-THF; 2) H2O2, NaOH 1) 03; 2) DMS
3. Complete the following reactions of the compound shown by drawing the correct products with CORRECT stereochemistry if important (10 pts). Br Br2 in H2O 1. O3 2. MegS HO H2/Pd OP A01018 1. Hg(OAc)2 in THF/Water 2. NaBH NaOH 1. BH3-THF 2. H2O2, NaOH estolqind, ( ym peroxyacid he anolbe o s HBr HBr/peroxide 1. OsO4 2. NAHSO3
10.
Provide the reagents necessary to complete the following
transformation. 13. Provide the structure of the major organic
product of the reaction below
10. Provide the reagents necessary to complete the following transformation. A. 1. BH3 THF 2. H202, HO B). H20, H2SO4 C. OsO4. H202 D. CH3CO3H E. 1. CH3CO3H 2. H, H20 11. Which of the following is the best reaction sequence to use if one wants to accomplish a Markovnikov addition of water to an alkene with...
Jos ou 2POMU PGJOM Which reagents are most likely to accomplish the reaction shown below? 4. ОН 1. BH, THF / 2. HO", H2O2, H2O H, H20 1. Hg(OAc)2, H2O, THF / 2. NaBH 1. Hg(OAc)2, CH3OH / 2. NaBHA NaOH, H20
What is the correct sequence of reactions that can achieve the
following multistep transformation?
List in the correct order. (No spaces nor commas in between
letters) eg: GAKJO
☺ > REAGENTS A Br2 B TosCl, pyr CHOH SO, cat DO Na 1 MeBr 2. EtBr 3. NaNH 1 eq E 1. OsO4 2. NaHSO3 F NaNHExcess GHO H NBS, hv I HBr ROOR L HBr M NaOtBu N NaOEt O NaoMe PETOH, H+ Cat Q NaCN RH, Lindlar's SH, Pt...
Practice Problem 11.15a
Identify reagents that can be used for the following
synthesis:
Draw the structure of compound A.
Practice Problem 11.15a Identify reagents that can be used for the following synthesis: он Compound A он correct. Identify reagent(s) that can be used to convert the starting alcohol into compound A. (1) TsCI, py; (2) NaOMe H2, Pt H2504 (1) TSCl, py; (2) t-BuOk SHOW ANSWER X Incorrect. Draw the structure of compound A 2 Edit Correct Identify reagent(s) that...
NaNH Br liq. NH 1) BH3, THF 2) H202, NaOH 1)Hg (OAC)2 B 2, THF-H2O 2) NaBH B SOCI Structure A Structure B
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