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QUESTION 6 Br CH,0 + + CH,OH + Br THF For this E2 reaction, indicate the effect that each change will have on the R...
For the SN1 reaction between water (H20) and t-butyl bromide (Me3C-Br), indicate the effect that each change below will...
For the SN1 reaction between water (H20) and t-butyl bromide (Me3C-Br), indicate the effect that each change below will have on the RATE of the reaction. Answers are either: rate will increase (1), rate will decreasse (D), or reaction rate will show no change (NC). Enter I, D, or NC in each blank. 1. The concentration of t-butyl bromide decreases. 2. The temperature of the reaction is raised. 3. The nucleophile is changed from H20 to NH3. 4.1-bromobutane is used...
3. Circle the reaction below which is faster in polar protic solvents. OH, ,0 A. CH,CH,CH,Br — CH,CH,CH,OH + Br or...
3. Circle the reaction below which is faster in polar protic solvents. OH, ,0 A. CH,CH,CH,Br — CH,CH,CH,OH + Br or CH,CH,CH,SH + Br B. CH CH.CH.BESH,RSH 4. Doubling the concentration of hydroxide in the reaction in problem #3A: A: causes the reaction mechanism to change. B: halves the rate of reaction. C: has no effect on the rate of reaction. D: doubles the rate of reaction. 5. Circle the reaction below which is faster. 70% H2O A. (CH3)3C-C 30%...
1. Draw all of the constitutional isomers that are formed in each elimination reaction and label...
1. Draw all of the constitutional isomers that are formed in each elimination reaction and label the mechanism as E2 or E1. a. 2-bromo butane reacts with methoxide b. 1-chloro-1-ethyl 2 methyl cyclopentane reacts with water 2. For which reaction mechanism are each of the following statements true? Mechanism S1, S2, E1 or E2. A statement may be true for one or more mechanisms a. The mechanism involves carbocation intermediates b. The mechanism has two steps C. The reaction rate...
For letters h & i : For each of the following reactions, predict the major mechanistic pathway (SN1/SN2/E1/E2...
For
letters h & i :
For each of the following reactions, predict the major
mechanistic pathway (SN1/SN2/E1/E2) and the major organic
products
1. (cont.) (h) НСОН CHB -CHBr HCOH - (0) CH,CH,CH,CH,Br- NH 2. For each of the following indicate which reaction will occur faster. Explain your reasoning. (No credit will be given for guesses) (a) The reaction of (CH),CBr with 0.001M aqueous NaOH or 0.10M aqueous NaOH (b) The reaction of 2-bromobutane with NaOH in DMSO or NaSH...
1. An alkyl halide which might be expected to undergo rearrangement under Sylor El conditions is: HAC Br A. B. [ CH...
1. An alkyl halide which might be expected to undergo rearrangement under Sylor El conditions is: HAC Br A. B. [ CH,Br c . CH-C-CH-CH, Br at would you acetylide, i. CH, CH, C-Br - CH CH, CH b) II CH р см, сен,сн, в. D. CH3-C-CH.CH -Br CH; в с. Task is to 13CH2C Br alkyl! 1.CH 2. Your task is to convert 2-chloropentane into l.pentene. Which reagents would you choose? a) NaOH/H2O b) KOH/CH3OH c) CH3ONa/CH3OH d) CH3CH2ONa/CH3CH2OH...
answer all 1. In each of the following, indicate which S2 reaction will occur faster. Explain...
answer all
1. In each of the following, indicate which S2 reaction will occur faster. Explain your reasoning. a. 1-bromo-2,2-dimethylpropane or 1-bromo-3-methylbutane with Nal in DMSO. b. 1-iodopentane with NaN, in ethanol or NaSCH, in ethanol, c. Reaction of isobutyl iodide with NaBr in acetone or in ethanol. 2. In each of the following, indicate which S, 1 reaction will occur faster. Explain your reasoning. a. Reaction of I-chloro-1-methylcyclohexane or 1-chloro-2-methylcyclohexane in aqueous ethanol. b. Reaction of 2-chloropentane or 3-bromohexane...
15. A student is studying the following El reaction, taking place in water as a solvent....
15. A student is studying the following El reaction, taking place in water as a solvent. Indicate what effect, if any, the following changes will make to the rate of the reaction. Explain your answers! (1 pt each) (CHs)3C-Br base (CHs)2c-CH2 a) Increasing the concentration of base. b) Changing the leaving group from Br to I. Switching to acetone as a solvent. c) Increasing the concentration of the alkyl halide. d) 1o. Synthesize the compound below from methyleyclohexane. (4 pts)...
Help with part e please! 3. Consider the following Sw1 reaction. CHg CH,-Ẻ-CHCH + HO ---...
Help with part e please!
3. Consider the following Sw1 reaction. CHg CH,-Ẻ-CHCH + HO --- ne bo pomem e no — a potom os CHE CH-C-CHÚCH + I" OH a. Draw a mechanism for this reaction using curved arrows. b. Draw an energy diagram. Label the axes, starting material, product, E, and . Assume that the starting material and product are equal in energy. c. Draw the structure of any transition states. d. What is the rate equation for...
Select which compound is the most reactive in an SN1 reaction Br Select one: O III...
Select which compound is the most reactive in an SN1 reaction Br Select one: O III Assuming no other changes, what is the effect of doubling both the alkyl halide and the nucleophile concentrations in the reaction below? for OH 79 + HB Select one: O a quadruples the rate b. triples the rate c. doubles the rate O d. no change e. rate is halved B. Select which compound is the most reactive in an SN 1 reaction Sel...
For the SN1 reaction between water (H20) and t-butyl bromide (Me3C-Br), indicate the effect that each change below will have on the RATE of the reaction. Answers are either: rate will increase (1), rate will decreasse (D), or reaction rate will show no change (NC). Enter I, D, or NC in each blank. 1. The concentration of t-butyl bromide decreases. 2. The temperature of the reaction is raised. 3. The nucleophile is changed from H20 to NH3. 4.1-bromobutane is used...
3. Circle the reaction below which is faster in polar protic solvents. OH, ,0 A. CH,CH,CH,Br — CH,CH,CH,OH + Br or CH,CH,CH,SH + Br B. CH CH.CH.BESH,RSH 4. Doubling the concentration of hydroxide in the reaction in problem #3A: A: causes the reaction mechanism to change. B: halves the rate of reaction. C: has no effect on the rate of reaction. D: doubles the rate of reaction. 5. Circle the reaction below which is faster. 70% H2O A. (CH3)3C-C 30%...
1. Draw all of the constitutional isomers that are formed in each elimination reaction and label the mechanism as E2 or E1. a. 2-bromo butane reacts with methoxide b. 1-chloro-1-ethyl 2 methyl cyclopentane reacts with water 2. For which reaction mechanism are each of the following statements true? Mechanism S1, S2, E1 or E2. A statement may be true for one or more mechanisms a. The mechanism involves carbocation intermediates b. The mechanism has two steps C. The reaction rate...
For
letters h & i :
For each of the following reactions, predict the major
mechanistic pathway (SN1/SN2/E1/E2) and the major organic
products
1. (cont.) (h) НСОН CHB -CHBr HCOH - (0) CH,CH,CH,CH,Br- NH 2. For each of the following indicate which reaction will occur faster. Explain your reasoning. (No credit will be given for guesses) (a) The reaction of (CH),CBr with 0.001M aqueous NaOH or 0.10M aqueous NaOH (b) The reaction of 2-bromobutane with NaOH in DMSO or NaSH...
1. An alkyl halide which might be expected to undergo rearrangement under Sylor El conditions is: HAC Br A. B. [ CH,Br c . CH-C-CH-CH, Br at would you acetylide, i. CH, CH, C-Br - CH CH, CH b) II CH р см, сен,сн, в. D. CH3-C-CH.CH -Br CH; в с. Task is to 13CH2C Br alkyl! 1.CH 2. Your task is to convert 2-chloropentane into l.pentene. Which reagents would you choose? a) NaOH/H2O b) KOH/CH3OH c) CH3ONa/CH3OH d) CH3CH2ONa/CH3CH2OH...
answer all
1. In each of the following, indicate which S2 reaction will occur faster. Explain your reasoning. a. 1-bromo-2,2-dimethylpropane or 1-bromo-3-methylbutane with Nal in DMSO. b. 1-iodopentane with NaN, in ethanol or NaSCH, in ethanol, c. Reaction of isobutyl iodide with NaBr in acetone or in ethanol. 2. In each of the following, indicate which S, 1 reaction will occur faster. Explain your reasoning. a. Reaction of I-chloro-1-methylcyclohexane or 1-chloro-2-methylcyclohexane in aqueous ethanol. b. Reaction of 2-chloropentane or 3-bromohexane...
15. A student is studying the following El reaction, taking place in water as a solvent. Indicate what effect, if any, the following changes will make to the rate of the reaction. Explain your answers! (1 pt each) (CHs)3C-Br base (CHs)2c-CH2 a) Increasing the concentration of base. b) Changing the leaving group from Br to I. Switching to acetone as a solvent. c) Increasing the concentration of the alkyl halide. d) 1o. Synthesize the compound below from methyleyclohexane. (4 pts)...
Help with part e please!
3. Consider the following Sw1 reaction. CHg CH,-Ẻ-CHCH + HO --- ne bo pomem e no — a potom os CHE CH-C-CHÚCH + I" OH a. Draw a mechanism for this reaction using curved arrows. b. Draw an energy diagram. Label the axes, starting material, product, E, and . Assume that the starting material and product are equal in energy. c. Draw the structure of any transition states. d. What is the rate equation for...
Select which compound is the most reactive in an SN1 reaction Br Select one: O III Assuming no other changes, what is the effect of doubling both the alkyl halide and the nucleophile concentrations in the reaction below? for OH 79 + HB Select one: O a quadruples the rate b. triples the rate c. doubles the rate O d. no change e. rate is halved B. Select which compound is the most reactive in an SN 1 reaction Sel...
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