HO CHI 2. Draw the structure of the following compounds. a. 3-methyl-3phenylbutanal b. 3-Oxobutanoic acid c. 1,3-Cy...
H H2C CH₃ 2. Draw the structure of the following compounds. a. 3-methyl-3 phenylbutanal H₂ b. 3-Oxobutanoic acid c. 1,3-Cyclohexanedione 3. Show how you can synthesize the compound below by H3C H3C
Two students are given 3-oxobutanoic acid below and asked to
prepare 2-methyl-3-oxobutanoic acid.
The first student recognizes this as the first step of the
acetoacetic ester synthesis. He treats the starting material with
sodium methoxide followed by methyl iodide. He isolates compound A,
but 1H NMR analysis shows this is not the desired material.
Elemental analysis shows it has the same molecular formula as the
2-methyl-3-oxobutanoic acid. What is compound A?
The second student recognizes an extra step is needed...
Provide the structure for each of the following compounds a. 3-Bromocyclobexanecarboxylic acid B N, N-Diethyl-4-ethylbeczamide c. Benzoic anhydride d. 3-Methybuthylethanoate e. 2-Ethyl-4-methylpertonirile Using cyclohexanol and any other reagents show how you will synthesize the following compounds.
1. Draw the structures of: a) (Z) 2-iodo-3-methyl-2-heptene b) cis non-3-en-5 yne Give the IUPAC name of the following compounds, including steochemistry. a) F CH2CH2Br CH3CE 2. a) Draw the most stable chair conformation of cis 1,3-difluorocyclohexane. b) Draw a Newman projection of 2-iodo-3-methylpentane looking down the 3. Compound X has the formula CoHB2Br4. Compound X reacts with excess H2/Pd to give CATHa6Bra. How many does compound X have? Show how you got your answer. rings 4. For each pair...
Draw the structure of each compound
1. Draw the structure of each compound: (a) cis-1,2-Cyclohexanediol (b) Isobutanol (c) 2,4,6-Trinitrophenol (d) (R)-2,2-Dimethyl-3-heptanol (e) Ethylene glycol (0) (s)-2-Methyl-1-butanol 2. Acid-catalyzed hydration of 3,3-dimethyl-1-butene produces 2,3-dimethyl-2-butanol. Show a mechanism for this reaction 3. Acid-catalyzed hydration of 1-methylcyclohexene yields two alcohols. The major product does not undergo oxidation, while the minor product will undergo oxidation. Explain. 4. Using 2-propanol as your only source of carbon, show how you would prepare 2-methyl- 2-pentanol. 5. Identify...
Draw the skeletal structure of the following compounds a. 3-ethyl-4-methyl-1,5-heptadiene b. 2,3-diethyl-3-methyl-1,4-pentadiene Determine the products of the following reactions. Also demonstrate the mechanism in each reaction
Determine and draw the structures of compounds A and B only. Do not draw the structure of compound X. Place each structure above its letter. HINT: Both A and B are esters. (10 points) LDA 1. compound B 1. NaOEt A х -78 °C 2. H30* OET 2. CH Br A B Create OscerSketch Answer 7 Draw a curved arrow mechanism for the following acid-catalyzed isomerization reaction. You must show all intermediates. (10 points) 1 H H20 Create OscerSketch Answer...
1. Draw structures for the following compounds: a) l-ethyl-2-methylcyclohexane b) 4-methyl hexanal c) N-N-dimethylpentanamide 2. What is the product of this bromination reaction? H2C-CH=CH-CH2-CH2-CH3 + Br2 3. What is the product of this oxidation reaction? OH H3C-CH-CH-CHg 10 Сн, 4. Consider the esterification reaction reaction below: H, SO H3C-CH2-CH2-CH2-C-OH + H2C-CH2-OH What organic compound is the reactant on the left? What organic compound is the reactant on the right? Draw the product of the reaction. What type of organic compound...
3. Write the structure of following organic compounds (15 points) 3-Chloro-5,7-dimethyl-4-cyclopropyl-2-octene 2-amino-3-methyl-2-nitro-butanal 2-Bromo-4-nitro-3-hexanol Aminomethanamide 2-Chloro-3-methyl-1-cyclopentanone 2-bromo-3-methyl-2-pentene 1-ethyl-3-methyl-2-propylcyclopentane 2-Keto-1,3-propandioic acid
This question deals with epoxide formation. (a) Draw the skeletal structure of(Z)-3-methyl-2-pentene (b) Draw the skeletal structure of one of the enantiomers (thatmeans you have to show wedge/dash bond(s)) formed when(Z)-3-methyl-2-pentene reacts with Br2 in the presence of water. (c) Draw the skeletal structure of the epoxide formed from yourproduct from (b) when it reacts with sodium hydroxide (you need toshow wedge/dash bond(s)). (d) Draw the skeletal structure of the major organic product from(c) when it reacts with sodium methoxide...