Provide the structure for each of the following compounds a. 3-Bromocyclobexanecarboxylic acid B N, N-Diethyl-4-ethylbeczamide c....
1) Draw the structure for each named compound: a) (Z)-N-ethyl-3-bromo-2-isopropyl-5- b) propanoyl chloride methyl-2-hexenamide c) benzoic anhydride d) (R)-3-chloro-4-ethylhexanoic acid e) ethyl 4-methylpentanoate f) pentanenitrile g) cyclohexanecarboxamide h) octyl butanoate 2) Provide an IUPAC name for each structure: b) 9 CH d) CH.CH нс снсон TH Page
(9) 8. Show how you would accomplish the following multistep synthesis: Synthesize the insect repellent N,N-diethyl-n-toluamide from m-toluic acid. Use compounds with no more than 5 carbons as your other reagents. NC CH 3 2 from
1. Write a structural formula for each of the following compounds: (36 pts) (a) m-chlorobenzoyl chloride (b) N-ethyl benzamide (c) dibenzalacetone (d) ethyl acetoacetate (e) 2-ethyl-1-butanamine (t) dibenzylamine 2. Write a structural formula for the principal organic product or products of each of the following reactions: (36 pts) (a) propanoyl chloride and sodium propanoate (b) acetic anhydride and 3-pentanol (c) acetaldehyde and sodium ethoxide (CH3CH2ONa) in ethanol solvent (d) cyclohexanone, benzaldehyde, and NaOH (e) 2-aminopropane and acetyl chloride in pyridine...
b) Write the structure of the following compounds (Fischer projection): (D)-serine, (S)-methionine c) Write the structure of the following tripeptide: H-Ala-Pro-Phe-OH 2. Determine the N-terminal amino acid of the above tripeptide (H-Ala-Pro-Phe-OH) using the Sanger method (chemical equation). 3. Starting from alanine and glycine synthetize the glycyl-alanine (H-Ala-Gly-OH) dipeptide using mixed anhydride coupling method with Boc (amino) and Bn (carboxyl) protecting groups (reagents, reaction conditions, chemical equations). 4. Starting from the appropriate aldehyde synthetize alanine using the Strecker synthesis (reactions,...
Organic Chem 142-01 2015 Dec 10 Name 6.Synthesis. Show how any THREE of the following compounds could be prepared, starting with benzene, toluene, cyclohexanol, or diethyl malonate, and any other necessary reagents. era mixture will give only the paroisomer) 18 points each CHO NHAc CO H оме Br NO2 7 of 9 Organic Chem 142-01 Name 2015 Dec 10 7. Write out THREE of the following reaction mechanisms. [10 points each] (a) Conversion of cyclopentanone to the oxime N-OH HCI...
1. Write the structural formula of each of the following co (1) m-chlorobenzoyl chloride; (b) p-ethylbenzamide: (©) (e) 2-ethyl-1-butanamine; (f) dibenzylamine; (g) a B-lacta the following compounds: (28 pts) Pethylben (s) acetoacetic ester; (d) diethyl malonate: of each of the following reactions: (30 pts) 2. Identify the principal organic product of each of the (a) acetic anhydride and 2-pentanol (b) 4-methyl-3-penten-2-one and ammonia in water solut er solution (c) acetophenone (methyl phenyi ketone) and benzalder (d) methyl butanoate and LDA...
Draw the skeletal structure of the following compounds a. 3-ethyl-4-methyl-1,5-heptadiene b. 2,3-diethyl-3-methyl-1,4-pentadiene Determine the products of the following reactions. Also demonstrate the mechanism in each reaction
(3 pts each, unless otherwise noted, 17 pts total) 1-5. Nomenclature: provide an acceptable name for each of the following compounds, but do NOT Google. 1. 2. 3. -CO No HN -CO,H COM 5. (5 pts) Name IUPAC ONLY. i HN-CHE H-C-N(CH)2 (4 pts each, unless otherwise noted, 16 pts total) 6-9. Structures: provide an acceptable structure for: 6. the isobutyl diester of B-bromopimelic acid (5 pts) 7. N-ethyl-B-ethyl-y-valerylactam. 8. benzoic B-chloropropionic anhydride (3 pts) 9. o-bromobenzoyl chloride
HO CHI 2. Draw the structure of the following compounds. a. 3-methyl-3phenylbutanal b. 3-Oxobutanoic acid c. 1,3-Cyclohexanedione 3. Show how you can synthesize the compound below by Witting reaction. HEC HEC
H H2C CH₃ 2. Draw the structure of the following compounds. a. 3-methyl-3 phenylbutanal H₂ b. 3-Oxobutanoic acid c. 1,3-Cyclohexanedione 3. Show how you can synthesize the compound below by H3C H3C