Homework Answers
Enantiomers are the non superimposable mirror images of each
other. They rotate the plane polarised light in opposite
directions.In the following case enantiomer are made by
interchanging the substituent on chiral carbons.
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1. For each of the following sugars: state the classification (by number of carbons and carbonyl type, like aldotetr...
Classify each monosaccharide by the type of carbonyl group and the number of carbons in the...
Classify each monosaccharide by the type of carbonyl group and the number of carbons in the chair - СН,ОН aldo. lect) HO- CH HO– –H HO– –H H- C-OH CH,OH pints CHOH References с н— Но— —ОН —н , сн,он | keo Oose "C
Culhydrates 1. Complete th Complete the table by classifying each sugar sugar (A, B, C, D)...
Culhydrates 1. Complete th Complete the table by classifying each sugar sugar (A, B, C, D) below based on carbonyl group and number of carbons (c.8. aldohexose, ketotriose, etc.). Classify them as an antiomer. Indicate the number of chiral carbons for each sugar. Sugar Classification based on carbonyl group and number of carbons Lor D enantiomer Number of chiral carbons н-с-он HO-6-H. н-с-он ін,он CH,OH C=0 HO-C-H н-с-он HO-C-H. ён,он снон c=0 | HO-C-H ін,он H-C-OH CH, OH CD 2....
Carbohydrates 1. Label each of the monosaccharides shown below as a triose, tetrose, pentoso, or hexose....
Carbohydrates 1. Label each of the monosaccharides shown below as a triose, tetrose, pentoso, or hexose. но CH OH HT -он - он Н - ОН но -н но -Н но -н нон сньон он но -н НОН CH OH нон нон нон снон CH OH сон сон H- OH H- -он OH cң, он н-с-он Сн,он снон 2. Label each of the monosaccharides shown above as a ketose or aldose. 3. Identify all of the chiral carbons in the...
Classify each of the following monosaccharides by the type of carbonyl group and the number of...
Classify each of the following monosaccharides by the type of
carbonyl group and the number of carbons (for example, a
monosaccharide with an aldehyde and three carbons is an
aldotriose).
ketotriose aldohexose CH2OH CH2OH aldotetrose 이 H CH OH ketotetrose I 운 우 ketopentose HH H1 ketohexose CHOH CH2OH aldopentose aldotriose
rever; mbine - you 13.78 Identify the Fischer projection A to D that matches each of...
rever; mbine - you 13.78 Identify the Fischer projection A to D that matches each of the following: (13.1, 13.3) a. the L enantiomer of mannose b. a ketopentose c. an aldopentose d. a ketohexose о но СН,ОН НЕОН CHOH С=0 НЕОН H- С=0 НЕ ОН НО -н НО-н Но Hн НО -Н НЕОН НО - H н -ОН НОН CHOH СН,ОН СН,ОН CH,OH -ОН dic D
4. For each sugar below, characterize the anomer if a monosaccharide or the glycosidic bond(s) if...
4. For each sugar below, characterize the anomer if a monosaccharide or the glycosidic bond(s) if a di- or polysaccharide (e.g., B,B-2,3; if there is more than one glycosidic bond, draw an arrow from each label to its corresponding bond). CH,OH CH2OH CH OН но н H Н H Он Н OH н OH Он Н ОН O H Но он b. a. OH H OH CH-OH O H Но ОН Н CH2OH CH2 CH2OH он OCH CH3 Но н...
5. Carbons and carbonyls. To which classes of sugars do the monosaccharides shown here belong? →...
5. Carbons and carbonyls. To which classes of sugars do the monosaccharides shown here belong? → 1 CHO н-с-он н-с-он CHO н-с-он н-с-он н-с-он Сн,он D-Ribose CHO н-с-он CH,OH D-Glyceraldehyde сн,он D-Erythrose о сн,он о сн,он сн,он Dihydroxyacetone н-с-он сн,он D-Erythrulose о сн,он о сн,он н-с-он н-с-он но-с-н н-с-он н-с-он Сн,он D-Fructose Сн,он D-Ribulose
Classify the following compounds as reducing sugars, non-reducing sugars, or neither: CH2OH CH2OH HONO CH2OH НО...
Classify the following compounds as reducing sugars, non-reducing sugars, or neither: CH2OH CH2OH HONO CH2OH НО НО CH2OH CH2OH НО- ONOH но но- HONO CH2OH но. HONO но от OCH3 OH но- ОН OH HO A с но но сHOH но снон CH OH CH2OH HONO ноу. НОА но -о но I H NH₂ HO но ОН N o="cs но і HO Но, IZ но го Е сн,он 1. non-reducing sugar - АА. C- B 2. reducing sugar - с...
1) SHOW WORK STEP By STEP below is Figure 7-3 Recognizing Epimers Using Figure 7-3, identify the epimers of (a) D-...
1) SHOW WORK STEP By STEP
below is Figure 7-3
Recognizing Epimers Using Figure 7-3, identify the epimers of (a) D-allose, (b) D-gulose, and (c) D-ribose at C-2, C-3, and C-4. Answer Epimers differ by the configuration about only one carbon. (a) D-altrose (C-2), D-glucose (C-3), D-gulose (C-4) (b) D-idose (C-2), D-galactose (C-3), D-allose (C-4) (c) D-arabinose (C-2), D-xylose (C-3) (a) D-Aldoses Three carbons Four carbons Five carbons но не HO -OH н-с-он CH, OH D-Glyceraldehyde но-с-н H-C-OH снион D-Threose...
12. Circle each anomeric carbon in the sugars below. (2 points) Which of the sugars below...
12. Circle each anomeric carbon in the sugars below. (2 points) Which of the sugars below is a reducing sugar? (1 point) Which sugar contains a glycosidic linkage? (1 point) CH-OH носно он н и носн,он они нон glucose fructose он Ин Н CH,он нон носно А он нон но/н,он и онон н sucrose 13. Extra credit: What type of enzyme catalyzes phosphate transfer? What type of enzyme usually catalyzes the rearrangement of a molecule? (2 points each)
Classify each monosaccharide by the type of carbonyl group and the number of carbons in the chair - СН,ОН aldo. lect) HO- CH HO– –H HO– –H H- C-OH CH,OH pints CHOH References с н— Но— —ОН —н , сн,он | keo Oose "C
Culhydrates 1. Complete th Complete the table by classifying each sugar sugar (A, B, C, D) below based on carbonyl group and number of carbons (c.8. aldohexose, ketotriose, etc.). Classify them as an antiomer. Indicate the number of chiral carbons for each sugar. Sugar Classification based on carbonyl group and number of carbons Lor D enantiomer Number of chiral carbons н-с-он HO-6-H. н-с-он ін,он CH,OH C=0 HO-C-H н-с-он HO-C-H. ён,он снон c=0 | HO-C-H ін,он H-C-OH CH, OH CD 2....
Carbohydrates 1. Label each of the monosaccharides shown below as a triose, tetrose, pentoso, or hexose. но CH OH HT -он - он Н - ОН но -н но -Н но -н нон сньон он но -н НОН CH OH нон нон нон снон CH OH сон сон H- OH H- -он OH cң, он н-с-он Сн,он снон 2. Label each of the monosaccharides shown above as a ketose or aldose. 3. Identify all of the chiral carbons in the...
Classify each of the following monosaccharides by the type of
carbonyl group and the number of carbons (for example, a
monosaccharide with an aldehyde and three carbons is an
aldotriose).
ketotriose aldohexose CH2OH CH2OH aldotetrose 이 H CH OH ketotetrose I 운 우 ketopentose HH H1 ketohexose CHOH CH2OH aldopentose aldotriose
rever; mbine - you 13.78 Identify the Fischer projection A to D that matches each of the following: (13.1, 13.3) a. the L enantiomer of mannose b. a ketopentose c. an aldopentose d. a ketohexose о но СН,ОН НЕОН CHOH С=0 НЕОН H- С=0 НЕ ОН НО -н НО-н Но Hн НО -Н НЕОН НО - H н -ОН НОН CHOH СН,ОН СН,ОН CH,OH -ОН dic D
4. For each sugar below, characterize the anomer if a monosaccharide or the glycosidic bond(s) if a di- or polysaccharide (e.g., B,B-2,3; if there is more than one glycosidic bond, draw an arrow from each label to its corresponding bond). CH,OH CH2OH CH OН но н H Н H Он Н OH н OH Он Н ОН O H Но он b. a. OH H OH CH-OH O H Но ОН Н CH2OH CH2 CH2OH он OCH CH3 Но н...
5. Carbons and carbonyls. To which classes of sugars do the monosaccharides shown here belong? → 1 CHO н-с-он н-с-он CHO н-с-он н-с-он н-с-он Сн,он D-Ribose CHO н-с-он CH,OH D-Glyceraldehyde сн,он D-Erythrose о сн,он о сн,он сн,он Dihydroxyacetone н-с-он сн,он D-Erythrulose о сн,он о сн,он н-с-он н-с-он но-с-н н-с-он н-с-он Сн,он D-Fructose Сн,он D-Ribulose
Classify the following compounds as reducing sugars, non-reducing sugars, or neither: CH2OH CH2OH HONO CH2OH НО НО CH2OH CH2OH НО- ONOH но но- HONO CH2OH но. HONO но от OCH3 OH но- ОН OH HO A с но но сHOH но снон CH OH CH2OH HONO ноу. НОА но -о но I H NH₂ HO но ОН N o="cs но і HO Но, IZ но го Е сн,он 1. non-reducing sugar - АА. C- B 2. reducing sugar - с...
1) SHOW WORK STEP By STEP
below is Figure 7-3
Recognizing Epimers Using Figure 7-3, identify the epimers of (a) D-allose, (b) D-gulose, and (c) D-ribose at C-2, C-3, and C-4. Answer Epimers differ by the configuration about only one carbon. (a) D-altrose (C-2), D-glucose (C-3), D-gulose (C-4) (b) D-idose (C-2), D-galactose (C-3), D-allose (C-4) (c) D-arabinose (C-2), D-xylose (C-3) (a) D-Aldoses Three carbons Four carbons Five carbons но не HO -OH н-с-он CH, OH D-Glyceraldehyde но-с-н H-C-OH снион D-Threose...
12. Circle each anomeric carbon in the sugars below. (2 points) Which of the sugars below is a reducing sugar? (1 point) Which sugar contains a glycosidic linkage? (1 point) CH-OH носно он н и носн,он они нон glucose fructose он Ин Н CH,он нон носно А он нон но/н,он и онон н sucrose 13. Extra credit: What type of enzyme catalyzes phosphate transfer? What type of enzyme usually catalyzes the rearrangement of a molecule? (2 points each)
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