1. Complete the following reactions. LAH POs 2. Complete the following reactions. DIBAL SOCI pyridine
1) Reactions. Provide the major products for each reaction sequence, account for stereochemistry 1) KMnO4, A 2) SOCI, CH2Cl2 3) 2 equiv. 1) ethylene oxide, THF 2) H3O+ workup Culi 3) DIBAL-H, THF 4) H3O+ workup 5) cat. TsOH, THF H3CCHE (c) HN COH 1) excess LAH, THE 2) H30+ workup 3) 1 equiv. EtN, DMF 4) pyridine i ( " culi , THF (d) PC Ph 2) H3O+/H2O workup 3) KMnO4, A 4) CH,OH, cat. H2SO4 5) cat. TsOH,...
QUESTION 4 What is the product of the following reactions? SOCI, (CH),CHOH pyridine
71. Predict the product for the following reaction. OH SOCI pyridine oooo SOCI IV
Yomon or no Гон 1. SOCI, Et3N 2. NaOAC LDA OH MsCI pyridine
19 Identify the product of following reaction. SOCI, CH3OH 1) CH2Mgl, excess CH3CH2CH2CH2C 2) H30* pyridine OH OH (A) CH2CH2CH2CH2CH-CH3 OH (B) CH3CH2CH2CH2CH-OCHz OH (C) CH3CH2CH2CH2C-OCH, CH3 OH (D) CH2CH2CH2CH2C-CHz CH,
please answer the following questions x SOCI xia 1. H.ot 1. Xhorx Me 2. CH,COCI, pyridine 1. DIBAH OMO 2. H,0 (vi) following oot. H,O+ (viii) 4. Starting with benzene and any other reagents show how you would prepare the following compounds.
The major product of the reaction below would be... OH 1) SOCI 2) CH3OH, pyridine Select one: O a. OCH3 ob. Pool OCH3 OC CI OCH3 Od. OCH3
B12 1.D SOCI Mg THE G- Light 3. A recent reporting forming cart than OH 2. H2O 1. LAH, THE H Cro MeOH - М 2. H2O excess 2. Fill in structures for A-O in the following reaction scheme part of which was recently reported in the chemical literature (JOC, 2011, 57-64). (15 x 3 = 45 pt) CH3OH KMnO4 1. LAH A B НО heat 2. H2O Cro, ci
Key Topics: Nucleophilic Substitution Reactions (SNI or SN2. Reactions using PBr3. SOCI, or TCI. In the empty boxes, draw the structure of the MAJOR organic product expected following each reaction shown. If the reaction involves an SN2 reaction (or involves an SN2 step in the overall mechanism) clearly show the correct stereochemistry that will be observed in the product. Two of the reactions will involve a carbocation rearrangement. (4pts for each correct Major product drawn) H*, MeOH HO NaOH NaCN...
5. Complete the following reactions by filling in the missing Reactants, Reagents, or MAJOR Product. If TWO products are equally formed show BOTH. 1. DIBAL 2. H307 Colon - ohne кон ОН OH NH2 LIAIH4 1. LDA / Dry THE - to 1.LA/D THE 1.1.2 Equiv. LDA/THF 2. Br Br2 acetic acid Pyridine Heat Nat Et EtOH single product