Consider the coordination compound K[Cr(CN).] : (i) Give the systematic name of the compound. (ii) What is the magnetic...
Consider the coordination compound Caz[Co(CN)6]: i. ii. Give the systematic name of the compound. What is the magnetic property of the complex (diamagnetic, strong or weakly paramagnetic)? (Use the appropriate d-orbital splitting diagram from the formula sheet to explain your answer) iii. Will the complex be a high-spin or low-spin complex?
(8 pts) 13. a. Give the crystal field splitting diagram for the complex ion, [Cr(CN)! with all d orbitals labeled and correct placement of electrons. b. Is the complex ion paramagnetic or diamagnetic? c. List the compounds in order of increasing wavelength that they would absorb light. (longest 2) (shortest A) [Cr(H2O)6]2. [CMNHJs产 [CrF6]4-, ,
Could you show how to do step by step,please? 3. Consider (Cr(CN).]*: (donor/acceptor) --CN is a _ (strong/weak)-field ligand because of interactions with the metal ion --In this complex, Cr-* is a d ion Therefore, the number of unpaired electrons in (Cr(CN).)" is Draw an orbital diagram showing the distribution of electrons: Calculate the spin-only magnetic moment of [Cr((CN).]" (in his units): Calculate (i) the Ligand-Field Stabilization Energy (as a function of Ac), (ii) the Coulombic energy (as a function...
Date: 1117 mework 10 - Ch. 21-23 A) CN B)NO c)r D) CO Name: E ) en 24. Place the ligands, CN-, Br., H2O, and OH-in order from least to greatest according ability to split the d orbital energy level. A) CN-, OH, H2O, Br- C) Br,H20, CN-, OH- B) Br., OH, H2O, CN- D) None of the above 25. The charge on the central metal ion in (Cr(NH3)(CO3)2+ is A)-1. B) 0. C) 1. D) 3. E) 5 26....
1. 2. systematic name of : [Co(NH3)5Cl] Cl2 Give the formula of each coordination compound. Include square brackets around the coordination complex. Do not include the oxidation state on the metal. Use parentheses only around polyatomic ligands. For ethylenediamine, use (en) in the formula. a) sodium tetrachloroplatinate(II) b) tris(ethylenediaminbaI) bromide c) pentaamminechlorochromium(lIl) chloride
1. Consider the coordination compound [Cr Cl(H20)4]C1.2H O. (i) What is the complex in the coordination compound and what is the charge in the complex ion? (ii) Identify the ligand(s) in the complex ion. 2. Calculate the number of moles of oxalate ion in 5.0 mL of 1.0 M H2C204 e oxidation number and coordination number of chromium
a. Predict the structure of [Cr(OH2)6]2+ - I wrote that the complex will undergo Jahn-Teller distortion, making the octahedral complex become tetragonal (don't know if that's correct) b. Account for the variation in the lattice enthalpy of Mn (2780 kJ/mol), Fe (2926 kJ/mol), Co (2976 kJ/mol), Ni (3060 kJ/mol), and Zn (2985 kJ/mol) flouride given that the metal center in all of the flourides is surrounded by an octahedral array of F-ions. c. Explain the effect on the d-orbital energies...
Consider the coordination compound triaquahydrexozine(II) nitrate. What is the charge on the complex ion ? 0 What isthecoordinationnumberofthemetal atom? L cops n Explicitly draw all H atoms. . You do not have to consider stereochemistry . Include non-bonding electrons for the ligands ? Do not include formal charges in your answer. Use the square brackets tool to show the overall charge of the complex e Do not include counter-ions, eg. Na, I, in your answer 0
5. The [NI(CN)412- ion has a square-planer geometry, whereas the INca diagrams (with d-orbital labels) for these twe complexes and determine if the compound is paramognetic or diamognet ion is tetrahedral. Drow the crystal field splitting 6. The absorption maximum for the complex ion (Co( Hale ccurs at 410 m. Predict the coler of this complex.Explain your reasoning. the Lewis structure of each and state whether the following are monodentate or bide ntate ligands a. c2042 (oxalate ion, ox) b,sar...
Could you show how to do step by step,please? 2. Consider (Cr((Cl).]": (donor/acceptor) --Cl is a strong/weak)-field ligand because of interactions with the metal ion --In this complex, Cr-* is a d ion Therefore, the number of unpaired electrons in Cr((Cl).].is Draw an orbital diagram showing the distribution of electrons: Calculate the spin-only magnetic moment of Cr((Cl).]" (in His units): Calculate (i) the Ligand-Field Stabilization Energy (as a function of Ao), (ii) the Coulombic energy (as a function of II.)...