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Why would concentrated hydrochloric acid be an inappropriate catalyst for the dehydration of cyclohexanol?

Why would concentrated hydrochloric acid be an inappropriate catalyst for the dehydration of cyclohexanol?

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Answer #1

In HCl, Cl​​​​​- is a good nucleophile. Hence elimination reactions compete with nucleophilic substitution reactions. HCl is not a good dehydrating agent like H2SO4.

As concentrated sulphuric acid is available as 98% and HCl is available as 37% . Hence in HCl, more amount of water is present than sulphuric acid. Hence HCl cannot acts as dehydrating agent.

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