Why would concentrated hydrochloric acid be an inappropriate catalyst for the dehydration of cyclohexanol?
In HCl, Cl- is a good nucleophile. Hence elimination reactions compete with nucleophilic substitution reactions. HCl is not a good dehydrating agent like H2SO4.
As concentrated sulphuric acid is available as 98% and HCl is available as 37% . Hence in HCl, more amount of water is present than sulphuric acid. Hence HCl cannot acts as dehydrating agent.
Why would concentrated hydrochloric acid be an inappropriate catalyst for the dehydration of cyclohexanol?
1. What is the function of the acid catalyst in promoting the dehydration of cyclohexanol?
why would concentrated hydrochloric acid be a poor choice as
the acid catalyst
the
too informatjon was not supposed to be there
[References) Draw the major product(s) of the following reactions including stereochemistry when it is appropriate (CH3)2CHCH2-CEC-H . 1 Br2 • Consider E/Z stereochemistry of alkenes. If there is more than one major product possible, draw all of them. Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right comer. • Separate multiple...
2. a. Both concentrated sulfuric acid and concentrated phosphoric acid are known to catalyze the conversion of cyclohexanol to cyclohexene via dehydration reaction. Concentrated hydrochloric acid, however, is not a viable option. Provide two reasons on what make sulfuric acid and phosphoric acid advantageous over hydrochloric acid. Look up additional information on these acids if needed. b. In preparation of the bromohydrin (trans-2-bromo-1-methylcyclohexanol) with bromine, side products dibromides shown below are often observed. This side reaction can be essentially avoided...
What is the major disadvantage of using concentrated sulfuric acid (or hydrochloric acid) rather than85% phosphoric acid for the dehydration of alcohols?
In the presence of an acid catalyst, cyclohexanol (100.16 g/mol) is dehydrated to give cyclohexane (82.14 g/mol) and water. A dehydration reaction starting with 3.23.2 g cyclohexanol produces 2.12.1 g cyclohexene. Calculate the percent yield for this reaction. Report your answer with two significant figures.
Convert Cyclohexanol to Cyclohexene via a Acid-Catalyzed Dehydration reaction 1. Why does the product ‘come over’ after being formed? Please think about the properties of the starting material and product. 2. If there was no acid present, would you expect to get a product? Why/why not? 3. If we start off with 10 molecules of the starting alcohol and only get an 80% yield, how many molecules will we find in the product flask? 4. Look up the concept of...
What would be the balanced equation for the addition of concentrated hydrochloric acid to cobalt chloride? CoCl2(aq) + CoCl2(aq) + ????
In the dehydration reaction of cyclohexanol to cyclohexene,
What problems would be encountered if 3-heptanol is used as a
starting material, (instead of cyclohexanol) and how can they be
circumvented?
OH O 04 + upon 4. O + ho + H3PO4 - + H2O cyclohexanol cyclohexene Figure 10. The dehydration of cyclohexanol to form cyclohexene.
Write equations for the mechanistic steps in the dehydration of cyclohexanol assuming an E1 mechanism. What is the role of phosphoric acid? Why is heat required?
In the Dehydration of Cyclohexanol (used Cyclohexanol to get Cyclohexene), we had to do distillation twice. Why is that? My TA said it had something to do with Azeotropes but I can't figure out why.