11.When cyclohexene is subjected to mercuration in methanol and the resulting mixture is reduced with sodium borohydride...
11.When cyclohexene is subjected to mercuration in methanol and the resulting mixture is reduced with sodium borohydride, the major organic product is: A) a meso ether. B) a 1:1 mixture of enantiomeric ethers. C) a meso diol. D) a 1:1 mixture of enantiomeric diols. E) methoxycyclohexane.
Homework Answers
Hence, the correct option is
E) methoxy cyclohexane .
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11.When cyclohexene is subjected to mercuration in methanol and the resulting mixture is reduced with sodium borohydride...
1) When 3-iodo-3-ethylpentane is treated with sodium methoxide in methanol, the major organic product is an...
1) When 3-iodo-3-ethylpentane is treated with sodium methoxide in methanol, the major organic product is an ___that is generated through an __mechanism. A) ether, Sw1 B) ether, SN2 C) ether, E1 D) alkene, E2 E) alkene, E1 2) Which compound produces only one alkene when treated with sodium methoxide? A) 2-chloro-2-methylpentane B) 3-chloro-3-ethylpentane C) 3-chloro-2-methylpentane D) 2-chloro-4-methylpentane E) 2-chloro-3-ethylpentane 3) What is the difference between Hoffmann and Zaitsev? When is Hoffmann favored?
1) When 3-iodo-3-ethylpentane is treated with sodium methoxide in methanol, the major organic product is an...
1) When 3-iodo-3-ethylpentane is treated with sodium methoxide in methanol, the major organic product is an ___ that is generated through an ____mechanism. A) ether, SN1 B) ether, Sn2 C) ether, E1 D) alkene, E2 E) alkene, E1 2) Which compound produces only one alkene when treated with sodium methoxide? A) 2-chloro-2-methylpentane B) 3-chloro-3-ethylpentane C) 3-chloro-2-methylpentane D) 2-chloro-4-methylpentane E) 2-chloro-3-ethylpentane 3) What is the difference between Hoffmann and Zaitsev? When is Hoffmann favored?
EXPERIMENT 11 THE MICROSCALE REDUCTION OF BENZIL WITH SODIUM BOROHYDRIDE INTRODUCTION Oxidation-reduction (redox) reactions occur in...
EXPERIMENT 11 THE MICROSCALE REDUCTION OF BENZIL WITH SODIUM BOROHYDRIDE INTRODUCTION Oxidation-reduction (redox) reactions occur in concert. One substance undergoes oxidation by donating electrons to another substance that is then reduced. In organic chemistry certain rules are followed in determining whether a particular substrate is being oxidized or reduced. Oxidation: The loss of hydrogen and/or gain of oxygen by a substrate Reduction: The gain of hydrogen and/or loss of oxygen by a substrate When an organic substrate is reduced, the...
19. What class of organic product results when 1-heptyne is treated with a mixture of mercuric...
19. What class of organic product results when 1-heptyne is treated with a mixture of mercuric acetate in aqueous sulfuric acid? A. aldehyde B. ketone C. diol D. ether E. carboxylic acid 20. Provide the major organic product of the reaction below. 1. Sia BH-THF (CHCHCH,CH.CHCH 2. HO HO
EXPERIMENT 11 THE MICROSCALE REDUCTION OF BENZIL WITH SODIUM BOROHYDRIDE INTRODUCTION Oxidation-reduction (redox) reactions occur in...
EXPERIMENT 11 THE MICROSCALE REDUCTION OF BENZIL WITH SODIUM BOROHYDRIDE INTRODUCTION Oxidation-reduction (redox) reactions occur in concert. One substance undergoes oxidation by donating electrons to another substance that is then reduced. In organic chemistry certain rules are followed in determining whether a particular substrate is being oxidized or reduced. Oxidation: The loss of hydrogen and/or gain of oxygen by a substrater Reduction: The gain of hydrogen and/or loss of oxygen by a substrate When an organic substrate is reduced, the...
10. On treatment with excess of sodium borohydride in methanol followed by treatment with aqueous acid,...
10. On treatment with excess of sodium borohydride in methanol followed by treatment with aqueous acid, which of the following carbonyl compounds is expected generate a racemic mixture of alcohols? CH, DO U 7. Starting with the compound with lowest pKa (t.e. most acidic), arrange the following in the order of increasing pKa values. OH (A) X <Y <Z <W (B) Z < X<Y <W (C) Y <Z < X <W (D) W < X <Y <Z (E) Z <Y...
a. Give the following alkyl halide produces a mixture of products when it reacts with sodium...
a. Give the following alkyl halide produces a mixture of
products when it reacts with sodium methoxide in methanol. Predict
all the reasonable products produced. Indicate which product is the
major product.
b. Give the mechanism of reaction from above that produces the
cis alkene by E2.
1. a. Give the following alkyl halide produces a mixture of products when it reacts with sodium methoxide in methanol. Predict all the reasonable products produced. Indicate which product is the major product....
What is the major organic product expected from the reaction of 2-cyclohexene-1-one with sodium phenylacetylate followed...
What is the major organic product expected from the reaction of 2-cyclohexene-1-one with sodium phenylacetylate followed by a mild acid workup? Select one: a. cyclohexanone b. 3-(benzylethynyl)-cyclohexanone c. 2-(phenylethynyl)-cyclohexenone d. cyclohex-2-yne-1-one e. 3-(phenylethynyl)-cyclohexanone
hi, please help me with number 7. thank you EXPERIMENT SEVEN SODIUM BOROHYDRIDE REDUCTION OF ACETOPHENONE...
hi, please help me with number 7. thank you
EXPERIMENT SEVEN SODIUM BOROHYDRIDE REDUCTION OF ACETOPHENONE HOCH, DISCUSSION The reduction of an aldehyde or ketone with sodium borohydride is straight forward and usually affords a high yield of the alcohol. The usual procedure (and the one employed in this experiment) involves dissolving the borohydride in 95% ethanol and adding the carbonyl compound to this solution. To ensure complete reaction, an excess of sodium borohydride is used. The reaction between sodium...
HW1. When the following reaction was run, the resulting organic product A. What is the structure...
HW1. When the following reaction was run, the resulting organic product A. What is the structure of product A? 14% Nal, acetone "Br Propose an SN2 mechanism that accounts for this interesting result: HW2. When the following reaction was run, the resulting organic products B and C were obtained. 1% AgNO3, EtOH a) Write the mechanism for the transformation and identify the organic products B and C: b) The relationship between B and C is: a. Enantiomeric b. Diastereomeric c....
1) When 3-iodo-3-ethylpentane is treated with sodium methoxide in methanol, the major organic product is an ___that is generated through an __mechanism. A) ether, Sw1 B) ether, SN2 C) ether, E1 D) alkene, E2 E) alkene, E1 2) Which compound produces only one alkene when treated with sodium methoxide? A) 2-chloro-2-methylpentane B) 3-chloro-3-ethylpentane C) 3-chloro-2-methylpentane D) 2-chloro-4-methylpentane E) 2-chloro-3-ethylpentane 3) What is the difference between Hoffmann and Zaitsev? When is Hoffmann favored?
1) When 3-iodo-3-ethylpentane is treated with sodium methoxide in methanol, the major organic product is an ___ that is generated through an ____mechanism. A) ether, SN1 B) ether, Sn2 C) ether, E1 D) alkene, E2 E) alkene, E1 2) Which compound produces only one alkene when treated with sodium methoxide? A) 2-chloro-2-methylpentane B) 3-chloro-3-ethylpentane C) 3-chloro-2-methylpentane D) 2-chloro-4-methylpentane E) 2-chloro-3-ethylpentane 3) What is the difference between Hoffmann and Zaitsev? When is Hoffmann favored?
EXPERIMENT 11 THE MICROSCALE REDUCTION OF BENZIL WITH SODIUM BOROHYDRIDE INTRODUCTION Oxidation-reduction (redox) reactions occur in concert. One substance undergoes oxidation by donating electrons to another substance that is then reduced. In organic chemistry certain rules are followed in determining whether a particular substrate is being oxidized or reduced. Oxidation: The loss of hydrogen and/or gain of oxygen by a substrate Reduction: The gain of hydrogen and/or loss of oxygen by a substrate When an organic substrate is reduced, the...
19. What class of organic product results when 1-heptyne is treated with a mixture of mercuric acetate in aqueous sulfuric acid? A. aldehyde B. ketone C. diol D. ether E. carboxylic acid 20. Provide the major organic product of the reaction below. 1. Sia BH-THF (CHCHCH,CH.CHCH 2. HO HO
EXPERIMENT 11 THE MICROSCALE REDUCTION OF BENZIL WITH SODIUM BOROHYDRIDE INTRODUCTION Oxidation-reduction (redox) reactions occur in concert. One substance undergoes oxidation by donating electrons to another substance that is then reduced. In organic chemistry certain rules are followed in determining whether a particular substrate is being oxidized or reduced. Oxidation: The loss of hydrogen and/or gain of oxygen by a substrater Reduction: The gain of hydrogen and/or loss of oxygen by a substrate When an organic substrate is reduced, the...
10. On treatment with excess of sodium borohydride in methanol followed by treatment with aqueous acid, which of the following carbonyl compounds is expected generate a racemic mixture of alcohols? CH, DO U 7. Starting with the compound with lowest pKa (t.e. most acidic), arrange the following in the order of increasing pKa values. OH (A) X <Y <Z <W (B) Z < X<Y <W (C) Y <Z < X <W (D) W < X <Y <Z (E) Z <Y...
a. Give the following alkyl halide produces a mixture of
products when it reacts with sodium methoxide in methanol. Predict
all the reasonable products produced. Indicate which product is the
major product.
b. Give the mechanism of reaction from above that produces the
cis alkene by E2.
1. a. Give the following alkyl halide produces a mixture of products when it reacts with sodium methoxide in methanol. Predict all the reasonable products produced. Indicate which product is the major product....
hi, please help me with number 7. thank you
EXPERIMENT SEVEN SODIUM BOROHYDRIDE REDUCTION OF ACETOPHENONE HOCH, DISCUSSION The reduction of an aldehyde or ketone with sodium borohydride is straight forward and usually affords a high yield of the alcohol. The usual procedure (and the one employed in this experiment) involves dissolving the borohydride in 95% ethanol and adding the carbonyl compound to this solution. To ensure complete reaction, an excess of sodium borohydride is used. The reaction between sodium...
HW1. When the following reaction was run, the resulting organic product A. What is the structure of product A? 14% Nal, acetone "Br Propose an SN2 mechanism that accounts for this interesting result: HW2. When the following reaction was run, the resulting organic products B and C were obtained. 1% AgNO3, EtOH a) Write the mechanism for the transformation and identify the organic products B and C: b) The relationship between B and C is: a. Enantiomeric b. Diastereomeric c....
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