Homework Answers
Question 10. Option D
Explanation: The product formed by the reduction of acetophenone with NaBH4 is 1-phenylethan-1-ol, which is a chiral molecule due to the presence of a chiral center. Hence, a racemic mixture of alcohols is generated.
Question 11. Option B
Explanation: Para-nitrophenol is the most acidic one, hence it has the most Ka value and the least pKa value.
Ortho-chlorophenol is more acidic than para-chlorophenol due to -I effect of Cl-group. Hence the pKa value of ortho-chlorophenol is less than that of para-chlorophenol.
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10. On treatment with excess of sodium borohydride in methanol followed by treatment with aqueous acid,...
hi, please help me with number 7. thank you EXPERIMENT SEVEN SODIUM BOROHYDRIDE REDUCTION OF ACETOPHENONE...
hi, please help me with number 7. thank you
EXPERIMENT SEVEN SODIUM BOROHYDRIDE REDUCTION OF ACETOPHENONE HOCH, DISCUSSION The reduction of an aldehyde or ketone with sodium borohydride is straight forward and usually affords a high yield of the alcohol. The usual procedure (and the one employed in this experiment) involves dissolving the borohydride in 95% ethanol and adding the carbonyl compound to this solution. To ensure complete reaction, an excess of sodium borohydride is used. The reaction between sodium...
1) What is the major organic product obtained from the following sequence of reactions? 1. (CH)...
1) What is the major organic product obtained from the following sequence of reactions? 1. (CH) CHCH.MOBI O CO HSÓ 2.H.O 2) What is the product of the following reaction? La noh to stor 3) What is the product of the following reaction? EtMgBr 4) What carbonyl compound and Grignard reagent could be used to prepare 2-butanol? CH.CHOCH.CH:Mgle CH.CH:CHO CHME CH.COCHCHMulle Only I Only II Only III Only I and II 6) What is the missing reagent in the reaction...
Experiment . the reduction of bencil (March 2020) Your name Sodium borohydride is a convert recent...
Experiment . the reduction of bencil (March 2020) Your name Sodium borohydride is a convert recent for the reduction of dehydes and ketones to 1" and 2 alcohols, respectively. The mechanism of the reaction - (below) is straightforward and is driven by boron's affinity for oxygen. In addition, given borohydride's remarkably low reactivity with OH groups under neutral and especially basic conditions, this reaction can be done in alcohol solvents. This means that (unlike LAH or Grignard reactions) no separate...
if anyone can check these answers for me and tell me which are right or wrong id appreciate it 0. How can p-aminobenzoic acid (a sunscreen) be synthesized from benzene? (Note that sometimes more...
if anyone can check these answers for me and tell me which are
right or wrong id appreciate it
0. How can p-aminobenzoic acid (a sunscreen) be synthesized from benzene? (Note that sometimes more than one isomer will be obtained, which is fine as long as the desired isomer is one of the major products.) several steps HOOC 4. Sn, HC 4.KMnO. .KMnO 4.Sn, HC 3.KMnO 3. CHCI, AİCİ, 3. Sn, HC . HNO, H SO 2. HNO,, H:SO4 1,...
please identify the unknown and write a derivative Unknown compound 3 Clear liquid Physcial Properties Solubility...
please identify the unknown and write a derivative
Unknown compound 3 Clear liquid Physcial Properties Solubility Dissolve in ethyl ether Not dissolved in water Boiling point 77 IR spectrum Transmitance 3000 1000 2000 Wavenumber cm-1) Classification Positive test in Alkaline Iron (III) Hydroxamate test test CLASSIFICATION TESTS These tests must be done together with known AND FOLLOW PROCEDURE IN YOUR TEXT CARBOXYLIC ACIDS are detected by teating aqueous solutions with limus or pH paper. Also, disolve In NaHCO with bubbles...
PREPARATION OF PHARMACEUTICALS - Fischer Esterification Reactions Q: Calculate the expected mass of both methyl salicylate and aspirin assuming 100% yield. EXPERIMENT7 PREPARATION OF PHARMACEUTICALS...
PREPARATION OF PHARMACEUTICALS - Fischer Esterification
Reactions
Q: Calculate the expected mass of both methyl salicylate and
aspirin assuming 100% yield.
EXPERIMENT7 PREPARATION OF PHARMACEUTICALS Fischer Esterification Reactions Almost 2500 years ago, physicians such as Hippocrates recommended that patients chew on the bark of the willow to alleviate pain. The active ingredient in willow bark was found to be salicin, a compound made of a molecule of salicyl alcohol bonded to a p-D-glucose molecule. In the stomach, the bond between...
What is the theoretical yield (in grams) and percent yield of your triphenylmethanol product in this...
What is the theoretical yield (in grams) and percent yield of your
triphenylmethanol product in this experiment? (Weight of
triphenylmethanol: 0.060g)
BACKGROUND AND THEORY The Grignard reaction was one of the first organometallic reactions discovered and is still one of the most useful synthetically. By reacting an organohalide (usually a bromide) with magnesium in ethereal solvent, carbon becomes a nucleophile. Grignard reagents are the starting points for the syntheses of many alkanes, primary, secondary, and tertiary alcohols, alkenes, and carboxylic...
hi, please help me with number 7. thank you
EXPERIMENT SEVEN SODIUM BOROHYDRIDE REDUCTION OF ACETOPHENONE HOCH, DISCUSSION The reduction of an aldehyde or ketone with sodium borohydride is straight forward and usually affords a high yield of the alcohol. The usual procedure (and the one employed in this experiment) involves dissolving the borohydride in 95% ethanol and adding the carbonyl compound to this solution. To ensure complete reaction, an excess of sodium borohydride is used. The reaction between sodium...
1) What is the major organic product obtained from the following sequence of reactions? 1. (CH) CHCH.MOBI O CO HSÓ 2.H.O 2) What is the product of the following reaction? La noh to stor 3) What is the product of the following reaction? EtMgBr 4) What carbonyl compound and Grignard reagent could be used to prepare 2-butanol? CH.CHOCH.CH:Mgle CH.CH:CHO CHME CH.COCHCHMulle Only I Only II Only III Only I and II 6) What is the missing reagent in the reaction...
Experiment . the reduction of bencil (March 2020) Your name Sodium borohydride is a convert recent for the reduction of dehydes and ketones to 1" and 2 alcohols, respectively. The mechanism of the reaction - (below) is straightforward and is driven by boron's affinity for oxygen. In addition, given borohydride's remarkably low reactivity with OH groups under neutral and especially basic conditions, this reaction can be done in alcohol solvents. This means that (unlike LAH or Grignard reactions) no separate...
if anyone can check these answers for me and tell me which are
right or wrong id appreciate it
0. How can p-aminobenzoic acid (a sunscreen) be synthesized from benzene? (Note that sometimes more than one isomer will be obtained, which is fine as long as the desired isomer is one of the major products.) several steps HOOC 4. Sn, HC 4.KMnO. .KMnO 4.Sn, HC 3.KMnO 3. CHCI, AİCİ, 3. Sn, HC . HNO, H SO 2. HNO,, H:SO4 1,...
please identify the unknown and write a derivative
Unknown compound 3 Clear liquid Physcial Properties Solubility Dissolve in ethyl ether Not dissolved in water Boiling point 77 IR spectrum Transmitance 3000 1000 2000 Wavenumber cm-1) Classification Positive test in Alkaline Iron (III) Hydroxamate test test CLASSIFICATION TESTS These tests must be done together with known AND FOLLOW PROCEDURE IN YOUR TEXT CARBOXYLIC ACIDS are detected by teating aqueous solutions with limus or pH paper. Also, disolve In NaHCO with bubbles...
PREPARATION OF PHARMACEUTICALS - Fischer Esterification
Reactions
Q: Calculate the expected mass of both methyl salicylate and
aspirin assuming 100% yield.
EXPERIMENT7 PREPARATION OF PHARMACEUTICALS Fischer Esterification Reactions Almost 2500 years ago, physicians such as Hippocrates recommended that patients chew on the bark of the willow to alleviate pain. The active ingredient in willow bark was found to be salicin, a compound made of a molecule of salicyl alcohol bonded to a p-D-glucose molecule. In the stomach, the bond between...
What is the theoretical yield (in grams) and percent yield of your
triphenylmethanol product in this experiment? (Weight of
triphenylmethanol: 0.060g)
BACKGROUND AND THEORY The Grignard reaction was one of the first organometallic reactions discovered and is still one of the most useful synthetically. By reacting an organohalide (usually a bromide) with magnesium in ethereal solvent, carbon becomes a nucleophile. Grignard reagents are the starting points for the syntheses of many alkanes, primary, secondary, and tertiary alcohols, alkenes, and carboxylic...
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