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Pure benzophenone melts at 48.1°C. Your sample of benzophenone began to freeze at 47.0°C. When you repeated this measurement,
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  • Explanation 1: the simple of benzophenone is not pure. The presence of impurities or humidity will cause a decrease in the melting point (or freezing point) of benzophenone. Small amounts of impurities will cause small decrease in freezing point, whereas high amounts of impurities cause a great decrease in freezing point.
  • Explanation 2: you are working at an altitude different from sea level. The melting points of compounds are reported considering the atmospheric pressure of 1 atm (that means that you are at level sea). If you are working at any altitude over sea level, the atmospheric pressure will be less than 1 atm. Then, melting point of benzophenone pure will be lower than 48.1 °C. This is because pressure changes modify the melting point and the boiling point of any substance.
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