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Item 29 29 of 32 Review Constants Periodic Table Calculate the change in Gibbs free energy for each of the sets of AN A S , a


Item 29 Calculate the change in Gibbs free energy for each of the sets of AHX ASP, and T given in the following problems. Par
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Answer #1

Part A : \Delta Gorxn = 211.7 kJ

Part B : \Delta Gorxn = -211.7 kJ

Part E : reaction in part A is : nonspontaneous

Part F : reaction in part B is : spontaneous

Explanation

Part A :

\DeltaGorxn = \Delta Horxn - (T) * (\DeltaSorxn)

\DeltaGorxn = (131 kJ) - (308 K) * (-262 J/K) * (1 kJ / 1000 J)

\DeltaGorxn = (131 kJ) + (80.696 kJ)

\DeltaGorxn = 211.7 kJ

Since \Delta Gorxn is greater than zero, therefore, reaction is nonspontaneous.

Part B :

\DeltaGorxn = \Delta Horxn - (T) * (\DeltaSorxn)

\DeltaGorxn = (-131 kJ) - (308 K) * (262 J/K) * (1 kJ / 1000 J)

\DeltaGorxn = (-131 kJ) - (80.696 kJ)

\DeltaGorxn = -211.7 kJ

Since \Delta Gorxn is less than zero, therefore, reaction is spontaneous.

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