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Physical Chemistry. Please show all your work. I'll rate. Thank you in advance!

4. Suppose a reaction occurs with a positive entropy, while its enthalpy is temperature independent. Raising the temperature

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Answer: As we know the equation of entropy, enthalpy and temperature as-

\DeltaG = \Delta H - T\DeltaS

If the \Delta H is independent of temperature then \Delta H can be ignored.

\DeltaG = - T\DeltaS

As per this equation if the value of Temperature (T) increases \Delta G value also increases towards more negative side.

As, more the negative \Delta G, more spontaneous is the reaction

hence the reaction is spontaneous this means product formation predominent.

Hence answer is (a) shifts the equilibrium towards product

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