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need help answering both Consider the hydrogen(s) attached to the carbon indicated with the red arrow...
Part 1: For each of the following structures, indicate the integration expected for the signal associated...
Part 1: For each of the following structures, indicate the
integration expected for the signal associated with the indicated
hydrogen(s).
a)
i)
ii)
iii)
iv)
b)
i)
ii)
iii)
c)
i)
ii)
iii)
d)
i)
ii)
iii)
iv)
v)
vi)
e)
i)
ii)
iii)
iv)
f)
i)
ii)
iii)
iv)
v)
vi)
Part 2: For each of the following structures, indicate the
coupling (a.k.a, splitting) pattern expected for the signal
associated with the indicated hydrogen(s) by placing the
appropriate letter(s)...
PLEASE HELP EXAMPLE V Ho Ho Ho He His PART 1: To receive credit, all handwriting...
PLEASE HELP
EXAMPLE V Ho Ho Ho He His PART 1: To receive credit, all handwriting must be CLEAR, NEAT, and CLEAN! Fill in the boxes below for each molecule, as demonstrated in the EXAMPLE. i) Draw ALL protons. ii) Label equivalent protons with the same subscript letter, in I alphabetical order from left to right or clockwise on the structure when possible (as demonstrated in RED in the EXAMPLE). iii) Indicate splitting by s=singlet, d=doublet, t-triplet, q-quartet, m=multiplet, dd-doublet...
MULTIPLE CHOICE QUESTIONS [25 marks) 1. Which of the following technique(s)can readily distinguish between: CHsCO2C...
MULTIPLE CHOICE QUESTIONS [25 marks) 1. Which of the following technique(s)can readily distinguish between: CHsCO2CH2CH3 and CH3CH2CO2CH A. NMR B. IR C. MS D. A and C 2. 1H nuclei located near electromagnetic atoms tend to berelative to iHi nuclei which are not. A. Shielded D. Deshielded C.Resonanced D. None of the above What splitting pattern is observed in the 1H NMR spectrum for the underlined hydrogens? CH3CH2CH(CI)CH2CH2OH A. doublet B. triplet C. quartet D.quintet 4. What splitting pattern is...
Question 1 The following reaction between 2-methylbut-2-ene and hydrogen bromide (HBr) is best described as what...
Question 1 The following reaction between 2-methylbut-2-ene and hydrogen bromide (HBr) is best described as what type of reaction? Refer to the Figure A) Addition B) Substitution C) Elimination D) Rearrangement Question 2 For the reaction in question 1, two products are possible- a major product, and a minor product. For the minor product, what is the splitting pattern for the added hydrogen (highlighted in red) that would be observed in the molecules HINMR spectrum? Refer to the Figure HBr...
i need help answering these qoustion plz???? Use the short grey sticks for single bonds and...
i need help answering these qoustion plz????
Use the short grey sticks for single bonds and the long flexible grey sticks for double and triple bonds. Note: In reality, single bonds are longer than double or triple bonds ) Fill in the table below Molecule # of lone pairs on central atom linear or bent? (Circle one) HO lincar benti SO lincar bent CO. bent lincar HCN bent lincar Question: Based on your answers in the table above and the...
PART 3 For each set of data on pages 5-9, calculate and record the degree of...
PART 3 For each set of data on pages 5-9, calculate and record the degree of unsaturation. Then use your problem solving skills to determine the chemical structure that is consistent with ALL of the data on each page. You are not required to label the spectra (but feel free to do so). This entire assignment is to be completed independently Suggestion for a general method to determine a chemical structure based on the provided molecular formula, IR, H-NMR and...
1151 VCL 11-8: Claisen Condensation -1 For this assignment, the target compound that you should s...
1151 VCL 11-8: Claisen Condensation -1 For this assignment, the target compound that you should synthesize is methyl acetoacetate. This is another carbonyl addition variation. Examine the product and determine which ester is the nucleophile and which is the electrophile. Keep in mind the mechanism and that you need to acidify the intermediate in order to isolate a neutral product. Synthesis Procedures 1. Start Virtual ChemLab and select Claisen Condensation-I from the list of assignments in the electronic workbook. After...
Only need help with 5,6,7 and mechanism FTIR and NMR Spectra After completing a reaction and...
Only need help with 5,6,7
and mechanism
FTIR and NMR Spectra After completing a reaction and working up the products, it is still necessary to confirm that the correct product was formed. The most common tools used for this analysis are Fourier Transform Infrared (FTIR) and Nuclear Magnetic Resonance (NMR) spectroscopy. In the virtual laboratory, 'H and C NMR spectra are available. Details on interpreting FTIR and NMR spectra are found in your textbook. Your instructor may or may not...
I need help with questions 5, 6, & 7. The FTIR and NMR is provided. I...
I need help with questions 5, 6, & 7. The FTIR and NMR is
provided. I also need help creating a reaction mechanism using the
following:
Starting material: 1,7-Dimethyl-heptanedioate
Solvent: Diethyl ether
Reagent: sodium methoxide
Product: 3-oxo-cyclohexane carboxylic acid methyl ester
THANK YOU!!!!!
Ö 11-11: Dieckmann Reaction For this assignment, the target compound that you should synthesize is 2-oxo-cyclohexane carboxylic acid methyl ester.This is an intramolecular carbonyl addition variation. Examine the product and determine which ester is the nucleophile and...
please complete the questions has not answering with clarification of the answer to any page Name...
please complete the questions has not answering with
clarification of the answer to any page
Name Lab Section _Date The Mole Concept and Atomic Weights The purpose of this activity is to better understand the concepts of relative atomic mass, counting by weighing and the mole. Percent composition and average atomic mass are included. Part I. Relative Atomic Masses and the Mole - Early Method When John Dalton proposed his atomic theory, he stated that the atoms of each element...
Part 1: For each of the following structures, indicate the
integration expected for the signal associated with the indicated
hydrogen(s).
a)
i)
ii)
iii)
iv)
b)
i)
ii)
iii)
c)
i)
ii)
iii)
d)
i)
ii)
iii)
iv)
v)
vi)
e)
i)
ii)
iii)
iv)
f)
i)
ii)
iii)
iv)
v)
vi)
Part 2: For each of the following structures, indicate the
coupling (a.k.a, splitting) pattern expected for the signal
associated with the indicated hydrogen(s) by placing the
appropriate letter(s)...
PLEASE HELP
EXAMPLE V Ho Ho Ho He His PART 1: To receive credit, all handwriting must be CLEAR, NEAT, and CLEAN! Fill in the boxes below for each molecule, as demonstrated in the EXAMPLE. i) Draw ALL protons. ii) Label equivalent protons with the same subscript letter, in I alphabetical order from left to right or clockwise on the structure when possible (as demonstrated in RED in the EXAMPLE). iii) Indicate splitting by s=singlet, d=doublet, t-triplet, q-quartet, m=multiplet, dd-doublet...
MULTIPLE CHOICE QUESTIONS [25 marks) 1. Which of the following technique(s)can readily distinguish between: CHsCO2CH2CH3 and CH3CH2CO2CH A. NMR B. IR C. MS D. A and C 2. 1H nuclei located near electromagnetic atoms tend to berelative to iHi nuclei which are not. A. Shielded D. Deshielded C.Resonanced D. None of the above What splitting pattern is observed in the 1H NMR spectrum for the underlined hydrogens? CH3CH2CH(CI)CH2CH2OH A. doublet B. triplet C. quartet D.quintet 4. What splitting pattern is...
Question 1 The following reaction between 2-methylbut-2-ene and hydrogen bromide (HBr) is best described as what type of reaction? Refer to the Figure A) Addition B) Substitution C) Elimination D) Rearrangement Question 2 For the reaction in question 1, two products are possible- a major product, and a minor product. For the minor product, what is the splitting pattern for the added hydrogen (highlighted in red) that would be observed in the molecules HINMR spectrum? Refer to the Figure HBr...
i need help answering these qoustion plz????
Use the short grey sticks for single bonds and the long flexible grey sticks for double and triple bonds. Note: In reality, single bonds are longer than double or triple bonds ) Fill in the table below Molecule # of lone pairs on central atom linear or bent? (Circle one) HO lincar benti SO lincar bent CO. bent lincar HCN bent lincar Question: Based on your answers in the table above and the...
PART 3 For each set of data on pages 5-9, calculate and record the degree of unsaturation. Then use your problem solving skills to determine the chemical structure that is consistent with ALL of the data on each page. You are not required to label the spectra (but feel free to do so). This entire assignment is to be completed independently Suggestion for a general method to determine a chemical structure based on the provided molecular formula, IR, H-NMR and...
1151 VCL 11-8: Claisen Condensation -1 For this assignment, the target compound that you should synthesize is methyl acetoacetate. This is another carbonyl addition variation. Examine the product and determine which ester is the nucleophile and which is the electrophile. Keep in mind the mechanism and that you need to acidify the intermediate in order to isolate a neutral product. Synthesis Procedures 1. Start Virtual ChemLab and select Claisen Condensation-I from the list of assignments in the electronic workbook. After...
Only need help with 5,6,7
and mechanism
FTIR and NMR Spectra After completing a reaction and working up the products, it is still necessary to confirm that the correct product was formed. The most common tools used for this analysis are Fourier Transform Infrared (FTIR) and Nuclear Magnetic Resonance (NMR) spectroscopy. In the virtual laboratory, 'H and C NMR spectra are available. Details on interpreting FTIR and NMR spectra are found in your textbook. Your instructor may or may not...
I need help with questions 5, 6, & 7. The FTIR and NMR is
provided. I also need help creating a reaction mechanism using the
following:
Starting material: 1,7-Dimethyl-heptanedioate
Solvent: Diethyl ether
Reagent: sodium methoxide
Product: 3-oxo-cyclohexane carboxylic acid methyl ester
THANK YOU!!!!!
Ö 11-11: Dieckmann Reaction For this assignment, the target compound that you should synthesize is 2-oxo-cyclohexane carboxylic acid methyl ester.This is an intramolecular carbonyl addition variation. Examine the product and determine which ester is the nucleophile and...
please complete the questions has not answering with
clarification of the answer to any page
Name Lab Section _Date The Mole Concept and Atomic Weights The purpose of this activity is to better understand the concepts of relative atomic mass, counting by weighing and the mole. Percent composition and average atomic mass are included. Part I. Relative Atomic Masses and the Mole - Early Method When John Dalton proposed his atomic theory, he stated that the atoms of each element...
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