please help solve For questions 1 - 5. predict the major organic products for the following...
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For questions 1 - 5. predict the major organic products for the following transformations. Clearly indicate formal charges and stereochemistry if applicable. The use of a squiggly bond is not permitted; all stereoisomers should be clearly indicated for full credit. OH 1. a) Croy, H,SO,,H,O (Jones reagent) b) workup 2. a) HCI (cat.), CH, OH b) workup Q2 1. a) Croy, pyridine, HCl, solvent (PCC) b) workup 2. a) HCI (cat.), CH, OH b) workup a) NaOH, solvent,...
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For questions 1-9, select the reaction conditions (A-1) which would create the major organic product(s) in the number of steps permitted in each box. a) H,50, (cat.), NH, b) workup a) Cro ,H, SOX, H,0 (Jones Reagent) b) workup a) H.SO(cat.), CH,OH b) workup a) H,50,(cat.),(CH), NH b) workup a) NaBH, CH,OH b) H20-workup a) Croy, pyridine, HCl, solvent (PCC) b) workup a) H, 50, (cat.), CH,CH,OH b) workup a)H,SO, (cat.), CH...
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ethylamine does not provide any product (1). However, when Ill is exposed to identical conditions, product IV is isolated as the major organic product. Using arrows to indicate the flow of electrons, explain the formation of IV from III by providing a step-by-step mechanism. Messy or incoherent steps/structures will receive reduced or zero credit. Clearly indicate formal charges and stereochemistry if applicable. a) excess CH, NH, solvent TOH b)H,0* - workup IL H This product...
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Question 10. Using arrows to indicate the flow of electrons, provide a step-by-step mechanism which relates the starting materials to the products. Messy or incoherent answers will result in reduced or zero credit. Clearly cross out or remove anything you do not wish graded. All protonations/deprotonations must be explicitly shown; use of "proton transfer or P.T." is not permitted, and will receive zero credit if used in error. Clearly indicate formal charges if applicable. a)H,50 (cat.),...
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19. (Extra credit: 4 pts each) Predict the major expected product or products of each reaction or reactions shown below. It is recommended that you show your reasoning, such as intermediate compounds produced in any multi-step sets of reactions for partial credit. If stereochemistry at any site is important, be sure to show it clearly. Partial credit for correct regiochemistry but wrong stereochemistry Br (1) Mg, Et2O, heat (2) add H2Co 4 040 4 (assume only...
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Clearly indicate stereochemistry and the presence of stereoisomers, if any. 1. Predict the products of the following reactions. a. 1) HBO i) LiAIHA EO 2) Mg ether ii) H2O workup i) 2 equiv. PhMgBr MgBr i) CO2 ii) H20 workup ii) aq. HCI workup
1. Predict the major organic products of the following reactions. Draw all stereoisomers that are formed. НО, OH 1 eq ,H2SO4 (assume H2O workup of reaction to neutralize product) 1. LDA 2. (assume H,O workup of reaction to neutralize product) 3. Hg(OAC)2 4. NaBH, EtOH 1eq HBr EtOH ambiente 1. Brz. CCL 2. NaOET, ETOH OH
Question : Predict the major and minor products for the following reactions: NASH -CH3 + 1 H30 HC b) NaOEt Question 6: Predict the major and minor products for the following reactions: NaOEt OTS - Tosylate (OTS) With on CHM 2210 CH3 NaOH H₂C O=O=O Question 7: Draw the plausible mechanism for each of the following transformations: CHE BECH HO HBr CH CH CH3 H₂C- conc. H,SO heat HC Insuu H Question 8 Which is the better retrosynthesis for the...
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1. Predict the major product of the reaction. Clearly indicate stereochemistry, if necessary (3 pts) H 1.9-BBN-H THE Me Me 2. NaOH H202 2. Provide reagents to achieve the shown multi-step transformations. (6 pts) H Me Me Br Br Me Br Br 3. Draw a detailed arrow-pushing mechanism for the following transformation. (4 pts) Ph Li(0) Ph Ph Ph NH30)
1. Predict the major product of the reaction. Clearly indicate stereochemistry, if necessary (3 pts) Ph H2 Lindlar cat. hexanes Me 2. Provide reagents to achieve the shown multi-step transformations. (6 pts) Br CH 3. Draw a detailed arrow-pushing mechanism for the following transformation. (4 pts) OME B OMe Me Me NaOH H2O2 Me Me H