For each of the sites specified in the following molecules, indicate whether the site is nucleophilic, electrophilic, or neither by dragging the appropriate label to the box pointing to the site.
The structure of various compound marked with different sites is given and these sites needs to be classified as electrophilic, nucleophilic and neutral. Firstly, identify the sites as electron rich and electron poor then, mark the electron rich site as nucleophilic and electron poor sites as electrophilic. The site which is neither rich in electron density nor poor in electron density should be marked as neutral.
Electrophilic sites are generally poor in electron density that is either they are positively charged or attached with the electronegative atom or groups that withdraws their electron density. Electrophilic means they the atom or compounds which have affinity for electrons. For instance, consider the following compound:
Nucleophilic sites are generally rich in electron density that is either they are negatively charged or attached with the electron donating groups that increases the electron density on the site. Atoms which contain lone pair also act as electron rich site. Nucleophilic means they the atom or compounds which have affinity for protons or positive charge. For instance, consider the following compound:
Neutral sites are neither attached with electron donating or electron withdrawing groups nor they contain positive or negative charge. Therefore, they are neither electrophilic nor nucleophilic. For instance, consider the following compound:
Write the structures of the compounds in which the sites are electron poor and a small positive charge is generated on them as shown below:
Write the structures of the compounds in which the sites are electron rich and a small negative charge is generated on them as shown below:
Write the structure of the compound having neutral site, that is, neither electrophilic nor nucleophilic as shown below:
Thus, the electrophile and nucleophile sites are shown below:
For each of the sites specified in the following molecules, indicate whether the site is nucleophilic,...
1. Label all electrophilic (El) and nucleophilic (Nu) sites on the following molecules. BYYY OH
18. Classify the following molecules in terms of how fast they will undergo nucleophilic aromatic substitution, label them as "fast S.Ar. Label the ones that would be fast under electrophilic aromatic substitution as "fast Ear. Those that would not react label as neither. NO,
8. Identify the nucleophilic and electrophilic sites (one of each) in the two reactants in the following reaction. HOME Гоме
3. Indicate the nucleophilic group and the electrophilic group in each of the following reactions, then draw curved arrows to show the electron flow: (a) H-N: H H-C H H-NH ٹیم مینم می
Indicate whether each of the following molecules R, S, Z or E. Label the substituents according to priority. The third molecule is a Fischer projection. Cl H2C SH H CH3 CH3 Label each pair of molecules as enantiomers, diasteromers, identical molecules constitutional isomers, or not isomers at all. No partial credit. H3C SH CH3 CH(CH3)2 H3C CH2CH2F CH(CH3)2 H3C CH2CH3 and H CH3 and H SH Cl HOH OH and CH3
Classify the circled atom as nucleophilic, electrophilic, or neither. Select one: O a. Nucleophilic O b. Electrophilic c. Neither Draw the mechanism for the following SN1 reaction. Indicate which of the following statements is true. Select all correct answers to receive full credit. Cl +NaF Select one or more: a. The mechanism involves only a loss of leaving group and a nucleophilic attack and no other steps. b. A carbocation rearrangement occurs. c. The first step is a proton transfer....
1. Complete the following exercises: A. Indicate whether each substituted benzene ring will produce predominantly ortho/para or meta products) after electrophilic aromatic substitution: B. Identify the molecule that can undergo nucleophilic aromatic substitution by addition/elimination:
1.(8) Draw the Lewis structures for the following molecules and for each molecule: 0) indicate the orbital rybridization on the central atom () predict the molecular shape and whether the molecule is polar or nonpolar (a) SiF4 (b) SF4 2.(8) The following energy diagrams show a slight variation for the relative energy of , and 13, molecular orbitals. (a) Use the appropriate diagram to build the electron configurations for Og and CO molecules: (label cach diagram correctly.) (b) For each...
16. For each of the following reactions, indicate the nucleophilic center and the electrophilic center. Draw curved arrows to indicate the movement of electrons and draw the reaction products. (a) carbonyl phosphate + ammonia carbamic acid + P : NH HO OPO,?- (b) NADH + acetaldehyde ethanol + NAD H R- NH H. CO -NH2 (c) 2 amino aciddipeptide + H20 NH NH
Use
curved arrows to indicate the flow of electrons for the following
elementary steps. label each step of the proper name such as Sn2,
E2, electrophile elimination, bond dissociation, coordination,
nucleophilic addition, electrophilic addition, or nucleophilic
elimination
These are the answers I had but they are incorrect... could
you explain which are correct?
4. Use curved arrow to indicate the flow of electrons for the following elementary steps. Label each-st with a proper name such as S 2, E2, electrophile...