please explain in detail . thank you in advance .
please explain in detail . thank you in advance . 3. (a) Draw both chair conformations...
2. (25 points) Draw the two chair conformations (in equilibrium) for (1R 3R)-1- butyl-3-ethylcyclohexane and determine the more stable conformation.
1. Draw the chair conformation for the following molecules: 이 2. Draw the most stable conformation for the following molecules: a) cis-1-ethyl-3-methylcyclohexane b) trans-1-tert-butyl-4-ethylcyclohexane c) (1R,2R,4S) 2,4-dimethyl-1-isopropylcyclohexane
2. (25 points) Draw the two chair conformations in equilibrium) for (1 R 3R)-1- butyl-3-ethylcyclohexane and determine the more stable conformation. 2. (25 points) Draw the two chair conformations (in equilibrium) for (1 R 3R)-1- butyl-3-ethylcyclohexane and determine the more stable conformation.
1(a). Draw both chair conformations of trans-1-chloro-2-methylcyclohexane. Compare stabilities. (b) .Draw both chair conformations of cis-1- chloro-2-methylcyclohexane.Compare stabilities. (c).Draw both chair conformations of cis-1,4-dimethylcyclohexane. Compare stabilities .
5. In each of the problems below, consider the E1 or E2 reaction occurs then show the mechanism and product or products. Label major and minor products where applicable. a. Reaction of 1,1-bromomethylcyclohexane and sodium ethoxide in ethanol Br CH, OH b. Reaction of (1R 2R) 1-bromo-2-methylcyclohexane and sodium ethoxide in ethanol. HINT: You should draw the ring in a chair conformation first. CHE + 0 *lller Сн, CH,CH-OH C. Reaction of (15,2R) 1-bromo-2-methylcyclohexane and sodium ethoxide in ethanol. HINT:...
9. Draw two different chair conformations of cyclohexanol, showing all hydropen atoms. Identify each position as axial or equatorial 10. Draw the most stable chair conformation of the following molecules, and estimate the amount of strain in each: (a) trans-1-Chloro-3-methylcyclohexane (b) cis-1-Ethyl-2-methylcyclohexane (c) cis-1-Bromo-4-ethylcyclohexane (d) cis-1-tert-Butylcyclohexane 11. Which isomer is more stable, cis-decalin or trans-decalin? Explain. 12. Glucose exists in two forms having a 36:64 ratio at equilibrium. Draw a skeletal structure of each, describe the difference between them and...
11. Build the chair and boat conformations and identify the most stable conformation. Identify the 1,3-diaxial interactions. 12. Draw the most stable conformation of (a) ethylcyclohexane (b) 3-isopropyl-1,1-dimethylcyclohexane (c) cis-1-tert-butyl-4-isopropylcyclohexane 13. Draw all possible conformations of 1,4-dimethylcyclohexane and identify the most stable conformation 14. (a) Draw both chair conformations of cis-1,2-dimethylcyclohexane, and determine which conformer is more stable. (b) Repeat for the trans isomer. (c) Predict which isomer (cis or trans) is more stable. 15. (a) Draw both chair conformations...
Your Turn Which Mechanism is it? 5. In each of the problems below, consider the E1 or E2 reaction occurs then show the mechanism and product or products. Label major and minor products where applicable. a. Reaction of 1,1-bromomethylcyclohexane and sodium ethoxide in ethanol CH, OH сн. b. Reaction of (1R 2R) 1-bromo-2-methylcyclohexane and sodium ethoxide in ethanol. HINT: You should draw the ring in a chair conformation first. CHE 90 -CH, CH,CH,OH C. Reaction of (15,2R) 1-bromo-2-methylcyclohexane and sodium...
1. Now construct cis-1,2-dimethylcyclohexane in the chair conformation and draw it. Perform the ring flip and draw that conformation. Which of the two conformations is preferred? This compound is meso, find the conformation that accounts for this? 2. Construct and draw trans-1-ethyl-2-methylcyclohexane in the chair conformation. Perform the ring flip and draw that conformation. Which conformation is preferred/most stable? Why? Construct and draw the cis isomer in the most stable chair conformation. Perform the ring flip and draw that conformation....
Draw both chair conformations of (1R,2S)-2-chlorocyclohexaneamine. Clearly label the most stable conformation, and provide a brief explanation for your choice.