Pagane le tollning Jm 2-cyclohesane. My ed mn henshp -co)H CHS From barcaldehyde propart Pron borcaldlhyde...
6. a. Synthesize cyclo diketo ne from CH3CHCOCHzCH2CH2COGH 3 / CH,o b. Use CH,COCH CO,CHs to synthesize 3-ethyl-2-hexanone. 7. a. React cyclohexanone with C,H O,CCO,C2Hs/ C2H$O b. Synthesize PhCH2NH2 from Phthalimide. 6. a. Synthesize cyclo diketo ne from CH3CHCOCHzCH2CH2COGH 3 / CH,o b. Use CH,COCH CO,CHs to synthesize 3-ethyl-2-hexanone. 7. a. React cyclohexanone with C,H O,CCO,C2Hs/ C2H$O b. Synthesize PhCH2NH2 from Phthalimide.
2. (3 points) Consider molecules shown below: CH3 CHs CH CHs CHs CI CCI CH CI CH CI- H-CCI H-CCI Н-с—н HCH H-CH H--CH H-CH H-CH HCCI CI H H Н-С—СI CI Cн, CHs CH CHs CH3 E D. C. A (a) Identify all pairs of diastereomers. CAACBE (b) Identify all meso compounds. (c) Identify all pairs of enantiomers. (A (810le AOLBO
Solve for #9 what is the condensed structural formula CH3 8) 2-butene Cu H CHs- CH-CHs or CHs CHCHC 9) 3-ethyl-3-methyl-1-hexene 10) 3-methylcyclohexene C1 He
Predict the relative order of the carbonyl stretching frequencies, ν(CO), for the three compounds (MeC5H4)Mn(CO)3, [(MeC5H4)Mn(CO)2(NO)](PF6), and [(MeC5H4)Mn(CO)(PPh3)(NO)](PF6) and briefly rationalize your answer.
Lindlar's catalyst H- HC H-C-cEc-CHs h) HgSo, HC-HC-c c-H it + Н,о H,SO amu O HyCHC-cc-CH +H.O Н С k) 1. КОН HyC HC-CC CH hot KMnO 2. HC H,C HC CEC CHy cold KMnO Lindlar's catalyst H- HC H-C-cEc-CHs h) HgSo, HC-HC-c c-H it + Н,о H,SO amu O HyCHC-cc-CH +H.O Н С k) 1. КОН HyC HC-CC CH hot KMnO 2. HC H,C HC CEC CHy cold KMnO
Mn(CO)6 can react with PPh3 under different condition to make 2 isomers (cis and trans). Answer the following:1. 1. Mn(CO)6 was reacted with triphenylphosphine (PPh3) and NaBH4, absolute ethanol to produce Mn(CO)4(PPh3)2. What is the balanced reaction for this? 2. Mn(CO)6 was reacted with triphenylphosphine (PPh3) and NaBH4, 1-butanol to produce Mn(CO)4(PPh3)2. What is the balanced reaction for this? 3. How can we tell which isomer is produced from each equation by the IR spectrum of the product? 4. Mn(CO)6...
system: (1) (CH2=CH-CHCH-COH (2) HO_CCHCH(CH2CH=CH,)CH2CH(CH3)CO,H (3) CH2CH(CO2H)CH(CO,H)CH,CO,H Enter the IUPAC name Enter the IUPAC name Enter the IUPAC name
2) Order the following alkenes from most stable to least stable Нас Нас с-сн, н,с Hас +C- Нас н CHs -CH3 H Hе most stable least stable (a) I (b) I (c) I ll (d) 7) Order the following C-H bonds from strongest to weakest. strongest weakest (a) (b) (c) II (d) 8) Which of the following is represents the lowest energy transition state for the addition of BH, to 2-methyl-1-propene? quCH «сHs нСи Нас (b) (a) Нив--н H H...
3. Determine the oxidation state for carbon in each species below: C,H, C,H,O 2- CO CO, CH
calculuate valence electrons for each complex (a) [Mn(H20)]3+ (d) [Fe(H20).]3+ (b) [Cr(H2O)6]2+ (e) [Co(NH3)4] * (h) [Pd(NH3).]4+ (c) [V(H2O).]2+ (1) [Ni(H2O)]2+ (1) [Re(CN).]3- (g) MoF6