calculuate valence electrons for each complex (a) [Mn(H20)]3+ (d) [Fe(H20).]3+ (b) [Cr(H2O)6]2+ (e) [Co(NH3)4] * (h)...
For each of the transition metal ions : (a) [Fe(H2O)4 ]3+ (b) [Mn(H2O)4 Cl2 ]+ (c) [Re(H2O)4 Cl2 ]+ (d) [Co(NH3)2 (en)2]2+ (i) Draw the structure of each transition metal complex. (ii) Determine the number of d electrons (iii) Draw the arrangement of d electrons in the ground state (iv) Calculate the LFSE (in units of deltao or deltaT ) for each complex
Name the following compounds: 5. a) CuCla]2 b) Cr(H20)(NH3)]2 c) [Cr(H2O)4(NH)] SO4 d) K3[Fe(CN)6]
A) , and in Co(NH3)4Cl 2]NO 3, the counter ion is In K 4[Fe(CN) 6], the counter ion is akt:cr b.kt; NO3- C. CN ; cr d. CN ; NO3 e. Fe2+, CO3+ B) How many ions are formed when [CO(NH 3) 5CICI 2 dissolves in water? a. 5 d. 4 e. 2 C) What is the oxidation state of the nickel atom in the Ni(CN) 53 complex ion? a. +1 b.+3 C. +2 d. +4 e. +0 ОООО oooo...
Arrange the following compounds in order of unpaired electrons? [Fe(NH3)612+ [FeCI. [Mn(H2O).]2+ O [Mn(H2O).P+ > [FeCl.14- >[Fe(NH3)612+ O [Fe(NH3).12+>[FeC1:14->[Mn(H20).12+ O [FeC1.14-> [Mn(H20),12+>[Fe(NH3).12+ O [Mn(H2O).]2+ > [Fe(NH3).12+>[FeC1.14- O [FeCl.14-> [Fe(NH3)612+->[Mn(H20).12+ O [Mn(H20).12+> [FeC1.14->[Fe(NH3),12+
Which of the following compounds can exhibit fac-mer isomerism? [V(NH3)2(H2O)4]2+ [Cu(CO)5I]+ [Cr(H2O)4Br2]+ [Ni(CO)5NO2]2+ [Fe(H2O)3(CO)3]3+
Predict which complex in each of the following pairs will have the lower energy d-d transition; give brief explanation of your reasoning: a. [Mn(CN)6] or [Mn(H20)6]3* b. Cr(PH3)6 or Cr(PF3)6 c. [Nb(H20)6]3+ or [Ta(NH3).]3+ d. [Ni(H20)4]+ or [Cu(H2O)4]3+
5. Name the following compounds: a) [CuCl4)? b) [Cr(H2O)(NH3)]*2 c) [Cr(H2O) (NH3)]SO4 d) K3 [Fe(CN)6]
Date: 1117 mework 10 - Ch. 21-23 A) CN B)NO c)r D) CO Name: E ) en 24. Place the ligands, CN-, Br., H2O, and OH-in order from least to greatest according ability to split the d orbital energy level. A) CN-, OH, H2O, Br- C) Br,H20, CN-, OH- B) Br., OH, H2O, CN- D) None of the above 25. The charge on the central metal ion in (Cr(NH3)(CO3)2+ is A)-1. B) 0. C) 1. D) 3. E) 5 26....
For each of the following transition metal complexes, determine the oxidation state of the metal, its coordination number, and the number of d electrons on that metal. (a) RuO4 (b) (CO(NH3).]3+ (c) [Cr(H2O).]8+ (d) Cr(H2O)3Cl2 (e) [Fe(H2O).]3+ (1) (Co(NH3).]2+ (9) MOCI (h) (Pt(CN)4]2- () [Mn(H2O).]2+ (1) Re(CO).Br (k) (Ag(CN 2] (1) [ReH9]?
4. Give chemical names for the following coordination complexes. a) [Cu(NH3)4]2+ b) [Pt(NH3). Cl]* c) [Mn(CN):)". d) (Co(en)2(PPha)]PO... e) [Ni(bipy)](NO3)2. 5. Give chemical formulas for the following coordination complexes. a) Triammineaquadichlorocobalt(III) chloride. b) Potassium diaquabis(oxalate)manganate(III). c) Tris(acetylacetonato Jiron(III). d) Tri--carbonylbis(tricarbonyliron(O)). e) Li-oxo-bis(pentaamminechromium(III)). 5. Draw a d-orbital energy-level diagram, and predict the number of unpaired electrons. a) [Fe(CN).] b) [Fe(H20):] c) (CoCil (tetrahedral) 6. Of the two complexes (a) (CoFs] and (b) (Coſen)] + one appears yellow and the other appears...