Question

Draw the expected organic product(s) when benzene is treated with each of the following alkyl halides in the presence of AlCl3. In each case, assume conditions have been controlled to favor monoalkylation

Draw the major product of the following compound. Cl 2 Edit Get help answering Molecular Drawing question Draw the major product of the following compound CI 2 Edit Draw the major product of the following compound Cl 2 Edit

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Answer #1
Concepts and reason

The concept used to solve this problem is determining the product from the reaction of benzene and given alkyl halides in the presence of by Fridel-Crafts reaction.

Fundamentals

Fridel-Crafts reaction:

Charls Friedel and James M. Crafts discovered new methods for the preparation of alkyl-benzene and acyl-benzene, these reactions are now called the Friedel-Crafts alkylation and acylation.

The general equation for a Fridel-Crafts alkylation is as follows:

The general equation for a Fridel-Crafts acylation is as follows:

AICI3
к
-CH3
нам

Part a

The given alkyl halide is as follows;

chlorocyclohexane

When the above alkyl halide is treated with benzene in presence of alkyl-benzene is form as follows:

HCI
benzene chlorocyclohexane
cyclohexylbenzene

Part b

The given alkyl halide is as follows;

нс
H3C CH3
2-chloro-2-methylpropane

When the above alkyl halide is treated with benzene in presence of alkyl-benzene is form as follows:

CH3
нс
+ HCI
AICI
+
CI
HzC CHE
benzene
2-chloro-2-methylpropane
tert-butylbenzene

Part c

The given alkyl halide is as follows;

H2C Y CI
CH3
1-chloro-2-methylbutane

When the above alkyl halide is treated with benzene in presence of alkyl-benzene is form as follows:

CH3 CH3
CH3
Hc-
Y
A ICZ
major
(2-methylbutan-2-yl)benzene
H2C
X
CH3
CH3
HCI
benzene
ene
1-chloro-2-methylbutane
minor
(2-meth

Ans: Part a

Thus,the product is.

Part b

Thus, the product isCH3
нск
CH3
.

Part c

Thus, the product is.

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