Question

please draw the intermediates and the arrows to show where the electrons are going. please state which reaction it is.

Documents attached: IR, H & 13C NMR Tables, AHo Tables, periodic Table and pKa Table. 1) Draw the major organic product for each of the following reactions. Be sure to designate the reglochemistry and stereochemistry when appropriate. (24 pts) (a) SO,CH3 Н.с Na Na. Acetone H (b) Br B2 Br (c) 04 (1) Hg(O2CCH3)2 H2O Ph (2) NaBH NaOH MacBook Pro

Answer 1

SO2CH3 tur Nat, No acetone Mechanism # 7+ SOZCI A Bu # The reaction is sucheophilic Substitution reaction. (b) Sale Brz mechanism + Br₂ 7 * Br The reaction is addition reaction

© [Hg (0₂ C CH3)2 -- Hg (Ac) Acool mercuric acetate 0 0 ) + tgcom) opnu rij Cae). mong cone) L. Ph cho NaBH a ph ph OH "OH Iph + tg (Al) - - F30" Hong Lpn & L L en OH This reaction is called oxynercuration-demercuration .. : an addition reaction.

в 2) 65, Гне - с. Нs , Н . и + '7 с , HS H2O2, Naolt ( 45 сла mechanism C+5 ch С, Н, - н/ G С2Н5 т NooH — С, Нs +02. В 2 B - - | 0 < - P5 ( 2 3 "С, Нs 67 с. (ун, ф7 (2н A 3 H OH NaOH ф, у , ну 13 + О, с (qH This is an addition type reaction,

OH ) osoa , Pyridine olt ) NaHSO3 to mechanism 1 osoa, Pyridine . P3 NaHSO4 Ho oh - ó o но HO OH # The reaction is an addition reaction or a dial formation reaction.

KMnO4, a 04/H20 mechanism 이 Mnog DH This is dio formation of kom almene by knmoq. This is sor followed by oxidative cleavage. Though the last mechanism is aniale uncertain. Thessit Step an addition reaction.