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11. The mass spectrum below is that of benzyl 3-methylbutanoate (see structure below). Provide a structure...
2. Match the electron impact (El) mass spectrum with the correct structure from the choices below. of the fragments in the El spectra of the following molecules (write the correct letter in the upper left-hand corner of the spectra). Draw the structure of the indicated fragments (*) С В OH H *(43) *(71) *(43) 100 HS--1 100- -N-113 во- 80- 60- 60- 40- 40- 20- 20- m/z m/z 3. Predict the molecular ion peak pattern (El spectrum low resolution) for...
2. Match the electron impact (El) mass spectrum with the correct structure from the choices below. ectra of the following molecules (write the correct letter in the upper left-hand corner of the spectra). Draw the structure of the indicated fragments (*) A OH *(43) *(71) * (43) 100- MS-NU-O1 Relative Intensity Relative Intensity 10 20 30 40 50 70 80 90 100 10 30 40 60 70 50 /z 60 /z m m
2. Draw the structure of the cation responsible for the base peak (m/z=58) in the mass spectrum of 3-aminopentane shown below: 3. Below is given the mass spectrum of a simple alkane. What is the chemical formula of the alkane? What is the name of the alkane? Explain how you determined the exact structure of the alkane from the observed fragments. 4. Below is a mass spectrum of an ester. Identify the ester. Consider that the dominant fragmentation pathway involves...
zene, C6H6? 12-23 Propose structures for compounds that fit the following data: al A ketone with M+ 86 and fragments at m/z 71 and m/z 43 h An alcohol with M+ = 88 and fragments at m/z 73, m/z 70, and m/z = 59 12-24 2-Methylpentane (C6H14) has the mass spectrum shown. Which peak represents M+? Which is the base peak? Propose structures for frag- ment ions of m/z 71, 57, 43, and 29. Why does the base peak have...
An unknown, non-branched saturated hydrocarbon has the mass spectrum below. What is the structure of the unknown hydrocarbon? 100. 57 71 85 50 29 113 127 141155 189 183 197 211 225 241 254 20 80 100 120 140 160 180 200 220 240 40 60 An unknown compound with formula CaHioO, gave a negative test with 2,4- dinitrophenylhy drazine; however, the unknown tested positive with the Jones reagent. When added to a solution of bromine dissolved in methylene, the...
5 The parent peak in the mass spectrum shown below is at 100 80 6o 40 C 20 10 20 3 40 070 90 m/z (a) m/z 58 (b) m/z -71 (c) m/z - 86 (d) m/z 43 6 In mass spectrometry of the following organic compound, which of the following fragmentation pathway is not likely to occur? H3C CH H3C (a) dehydration (b) Alpha-cleavage (c) McLafferty rearrangement (d) All of these
Please interpret the mass spectrum of benzaldehyde, 3-nitro- to identfiy the structure of the molecule. 9W2 100 80 60 20- 0 100 125 150 75 25 50 m/z We were unable to transcribe this image
Deduce the ester compound structure with M/Z=136 on this mass spectrum; significant peaks at 51, 77, 105, 136. Relative Abundance M(136) 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135 140 mz
18. The mass spectrum of 2-methylpentan-3-ol is shown below. Draw the structure of the fragment ions of m/z= 73 and 59. Relative abundance (%) TTT 10 20 80 80 100 120 mi
Name: Starting with the mass spectrum of n-heptane What is the molecular ion? What fragment is lost to generate the ion with m/z =71? What cation does the peak at m/z = 43 represent? What group does the spacing between each set of ions represent? Why is the peak at (M-15), corresponding to loss of -CH3 so small? Draw the structure of 2,4-dimethylpentane What is the structure of the ion responsible for m/z = 85? Relative Intensity What is the...