Homework Answers
Option 1. is the right answer. Because in 1. the wavefunction is
symmetric (changing the position of r1 and r2 doesn't change
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The lowest energy unnormalized wave function of H molecule is (ri and r2 the distances between...
(1) The ground-state wave function for the electron in a hydrogen is given by ls 0...
(1) The ground-state wave function for the electron in a hydrogen is given by ls 0 Where r is the radial coordinate of the electron and a0 is the Bohr radius (a) Show that the wave function as given is normalized (b) Find the probability of locating the electron between rF a0/2 and r2-3ao/2. Note that the following integral may be useful n! 0 dr =-e re /a roa r a Ta
SMA #8: Bohr and Schrödinger Models of Hydrogen Here we investigate the relationship between the Schrödinger...
SMA #8: Bohr and Schrödinger Models of Hydrogen Here we investigate the relationship between the Schrödinger and Bohr models of hydrogen-like atoms, following our work in class on both 9 1. Using the appropriate Schrödinger wavefunctions, compute the most probable electron-proton radii (i.e., distances) for 1s, 2p, and 3d states. Do these agree with the corresponding Bohr radii? Hint #1: Remember to maximize the "radial distribution function" P(r) = [rR(r)], i.e., to include the radial Jacobian factor (r2) in your...
3 At a given time, the normalised wave function for a particle in a one-dimensional infinite...
3 At a given time, the normalised wave function for a particle in a one-dimensional infinite square well -a < x < a is given by 2 sin2 V inside the well and zero outside. Find the probability that a measurement of energy yields the eigenvalue En. (Hint: use data on page 6.) [6] Useful Data and Formulas = 1.60 x 10-19 C Elementary charge e h/2T=1.05 x 10-34 Js Planck's constant 3.00 x 108 m s-1 Speed of light...
need # 4 or 5 o Vibrational spectroscopy of the NO molecule (with absorption at 1878 cm isotope masses of No14 and 0-16, respectively) reveals Assuming that this transition represents the energy s...
need # 4 or 5
o Vibrational spectroscopy of the NO molecule (with absorption at 1878 cm isotope masses of No14 and 0-16, respectively) reveals Assuming that this transition represents the energy spacing between vibrational energy levels, calculate the force constant of the bond Assuming that the "N"O molecule has a bond with the same force constant as in part a, predict the position (in cm) of the absorbance peak for this molecule. 1. a. b 2. Normalize the first...
Suppose at a certain time to the wave function is, Ψ(x,6) N for all x between...
Suppose at a certain time to the wave function is, Ψ(x,6) N for all x between the values ofx = 1 cm and x = 2 cm. For all values ofx outside the interval [12] the wave function is zero. a) Normalize the wave function. (Solve for N). Pay attention to units! b) Sketch the probability density V(x,/,)(x, as a function of x c) What is the probability of finding the electron between 1.5 cm and 2.0 cm? d) What...
Consider the dimensionless harmonic oscillator Hamiltonian, (where m = h̄ = 1). Consider the orthogonal wave...
Consider the dimensionless harmonic oscillator Hamiltonian,
(where m = h̄ = 1).
Consider the orthogonal wave functions
and
, which are eigenfunctions of H with eigenvalues 1/2 and 5/2,
respectively.
with p=_ïda 2 2 We were unable to transcribe this imageY;(r) = (1-2x2)e-r2/2 (a) Let фо(x-AgVo(x) and φ2(x) = A2V2(x) and suppose that φ。(x) and φ2(x) are normalized. Find the constants Ao and A2. (b) Suppose that, at timet0, the state of the oscillator is given by Find the constant...
2. The hydrogen atom [8 marks] The time-independent Schrödinger equation for the hydrogen atom in...
2. The hydrogen atom [8 marks] The time-independent Schrödinger equation for the hydrogen atom in the spherical coordinate representation is where ao-top- 0.5298 10-10rn is the Bohr radius, and μ is the electon-proton reduced mass. Here, the square of the angular momentum operator L2 in the spherical coordinate representation is given by: 2 (2.2) sin θー sin θ 00 The form of the Schrödinger equation means that all energy eigenstates separate into radial and angular motion, and we can write...
The wave function for a hydrogen atom in the 2s state is psi_2s® = 1/squareroot 32...
The wave function for a hydrogen atom in the 2s state is psi_2s® = 1/squareroot 32 pi a^3 (2-r/a) e^-r/2a. In the Bohr model, the distance between the electron and the nucleus in the n=2 state is exactly Calculate the probability that an electron in the 2s state will be found at a distance less than 4a from the nucleus. P=
1) (35 points) The wave function for a particle moving along x axis between the limits 0 and L is: (x)-C sin (nx xL) where n are 1, 2, 3, A) Determine the normalization constant C B) Why can'...
1) (35 points) The wave function for a particle moving along x axis between the limits 0 and L is: (x)-C sin (nx xL) where n are 1, 2, 3, A) Determine the normalization constant C B) Why can't n take the value of 0, briefly explain C) For n-3 determine the values of x (in terms of L) that correspond to a maximum or a minimum in the wave function D) For n-3 determine the values of x (in...
The normalized wave function for a hydrogen atom in the 2s state is
( 25 marks) The normalized wave function for a hydrogen atom in the \(2 s\) state is$$ \psi_{2 s}(r)=\frac{1}{\sqrt{32 \pi a^{3}}}\left(2-\frac{r}{a}\right) e^{-r / 2 a} $$where \(a\) is the Bohr radius. (a) In the Bohr model, the distance between the electron and the nucleus in the \(n=2\) state is exactly \(4 a\). Calculate the probability that an electron in the \(2 s\) state will be found at a distance less than \(4 a\) from the nucleus. (b) At what value...
(1) The ground-state wave function for the electron in a hydrogen is given by ls 0 Where r is the radial coordinate of the electron and a0 is the Bohr radius (a) Show that the wave function as given is normalized (b) Find the probability of locating the electron between rF a0/2 and r2-3ao/2. Note that the following integral may be useful n! 0 dr =-e re /a roa r a Ta
SMA #8: Bohr and Schrödinger Models of Hydrogen Here we investigate the relationship between the Schrödinger and Bohr models of hydrogen-like atoms, following our work in class on both 9 1. Using the appropriate Schrödinger wavefunctions, compute the most probable electron-proton radii (i.e., distances) for 1s, 2p, and 3d states. Do these agree with the corresponding Bohr radii? Hint #1: Remember to maximize the "radial distribution function" P(r) = [rR(r)], i.e., to include the radial Jacobian factor (r2) in your...
3 At a given time, the normalised wave function for a particle in a one-dimensional infinite square well -a < x < a is given by 2 sin2 V inside the well and zero outside. Find the probability that a measurement of energy yields the eigenvalue En. (Hint: use data on page 6.) [6] Useful Data and Formulas = 1.60 x 10-19 C Elementary charge e h/2T=1.05 x 10-34 Js Planck's constant 3.00 x 108 m s-1 Speed of light...
need # 4 or 5
o Vibrational spectroscopy of the NO molecule (with absorption at 1878 cm isotope masses of No14 and 0-16, respectively) reveals Assuming that this transition represents the energy spacing between vibrational energy levels, calculate the force constant of the bond Assuming that the "N"O molecule has a bond with the same force constant as in part a, predict the position (in cm) of the absorbance peak for this molecule. 1. a. b 2. Normalize the first...
Suppose at a certain time to the wave function is, Ψ(x,6) N for all x between the values ofx = 1 cm and x = 2 cm. For all values ofx outside the interval [12] the wave function is zero. a) Normalize the wave function. (Solve for N). Pay attention to units! b) Sketch the probability density V(x,/,)(x, as a function of x c) What is the probability of finding the electron between 1.5 cm and 2.0 cm? d) What...
Consider the dimensionless harmonic oscillator Hamiltonian,
(where m = h̄ = 1).
Consider the orthogonal wave functions
and
, which are eigenfunctions of H with eigenvalues 1/2 and 5/2,
respectively.
with p=_ïda 2 2 We were unable to transcribe this imageY;(r) = (1-2x2)e-r2/2 (a) Let фо(x-AgVo(x) and φ2(x) = A2V2(x) and suppose that φ。(x) and φ2(x) are normalized. Find the constants Ao and A2. (b) Suppose that, at timet0, the state of the oscillator is given by Find the constant...
2. The hydrogen atom [8 marks] The time-independent Schrödinger equation for the hydrogen atom in the spherical coordinate representation is where ao-top- 0.5298 10-10rn is the Bohr radius, and μ is the electon-proton reduced mass. Here, the square of the angular momentum operator L2 in the spherical coordinate representation is given by: 2 (2.2) sin θー sin θ 00 The form of the Schrödinger equation means that all energy eigenstates separate into radial and angular motion, and we can write...
The wave function for a hydrogen atom in the 2s state is psi_2s® = 1/squareroot 32 pi a^3 (2-r/a) e^-r/2a. In the Bohr model, the distance between the electron and the nucleus in the n=2 state is exactly Calculate the probability that an electron in the 2s state will be found at a distance less than 4a from the nucleus. P=
1) (35 points) The wave function for a particle moving along x axis between the limits 0 and L is: (x)-C sin (nx xL) where n are 1, 2, 3, A) Determine the normalization constant C B) Why can't n take the value of 0, briefly explain C) For n-3 determine the values of x (in terms of L) that correspond to a maximum or a minimum in the wave function D) For n-3 determine the values of x (in...
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