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1. Predict the product(s) using the same alkens reactant for the following reactions PUC CH,CI, Bry...
3. Predict the product(s) using the same alkene reactant for the following reactions: HB H.O, hv...
3. Predict the product(s) using the same alkene reactant for the following reactions: HB H.O, hv H.0/H,0 1, HE, THI | 0 2. NaBH,/NaOH 1. B.H/THF 2. H.O./NaOH KMnO,H,O cold 1. Oso 2. NaHSO, 1. KMnO,/OH/heat 2. H,0 1. O,CH,CI 2. Zn/H,
3. Predict the product(s) using the same oduct(s) using the same alkens reactant for the following...
3. Predict the product(s) using the same oduct(s) using the same alkens reactant for the following reactions CH,CI, H,0 CI, CH,OH HI DB HBr H.O./hy H,O/H,0 1. Hg.THF-H,0 2. NaBH/NaOH 1. B.H/THF 2. H.O./NaOH KMnO,/H,0 cold 1. Oso 2. NaHSO, 1. KMnO/OH/heat 2. H,0 1. O,/CH,CI, 2. Zn/H,0
4. Predict the product(s) using th using the same skene reactant for the following reactions 10...
4. Predict the product(s) using th using the same skene reactant for the following reactions 10 CH,CI Br CH,OH HI DBE LIB H.Ohv H.O/H,0 1. Hg. THF-H,O 2. NaBH/NaOH 1. B.H/THF 2. H.OX/NaOH KMnO/H,O cold 1. Os 2. NaHSO, 1. KMnO/OH/heat 2. H,0 1. O,/CH,CI, 2. Zn/H,O
2. Predict the product(s) using the same alkene reactant for the following reactions: H,O, hv H5OH,O...
2. Predict the product(s) using the same alkene reactant for the following reactions: H,O, hv H5OH,O 1, HE. THI -H0 2. NaBH,/NaOH 1. B H/THF 2. H.O./NaOH KMnO /H,0 cold 1. Oso 2. NaHSO 1. KMnO/OH heat 2. H,0 1. O,/CH,CI, 2. Zn/H,0 1.0, 2. H,O/OH
Predict the product(s) using the same alkene reactant for the following reactions: 2. н, (a) Pt/C...
Predict the product(s) using the same alkene reactant for the following reactions: 2. н, (a) Pt/C D, (b) Pt/C Cl, (c) CH,Cl, Br, (d) Н.о Cl, (e) CH,OH HI (0 DBr (g) НВr (h) нолу ноно (0) 1. Hg". THF-H,O 2. NaBH/NaOH 1. В, Н, ТHF (k) 2. H,O/NaOH кMпо, H,о (I) cold 1. OsO, (m) 2. NaHSO, 1. KMnO/OH/heat (n) 2. Н.О" 1. 0/CH,CI, (o) 2. Zn/H,O 1. O, (p) 2. H.о/он
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions...
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
Provide the major product(s) for the following reactions: Show Stereochemistry when necessary (10 points total) Br...
Provide the major product(s) for the following reactions: Show Stereochemistry when necessary (10 points total) Br HBr CH2CI Br2 HBr Но ROOR CH,OH Н,о н* Н,о° 1) Hg(O,CCF3)2 CH,OH 1) BН, THF 2) H,О, NaOH, Нао 2) NaBH, NaOH 1) Hg(OAc) Н0, THF/ Hа Pd/C 2) NaBH, NaOH
1. Provide the major organic product(s) for each of the following reactions: 1) HNOZ/H, SO 2)...
1. Provide the major organic product(s) for each of the following reactions: 1) HNOZ/H, SO 2) Sn/HCl(aq) 3) HO 1) (CH3)2CHCI/AICI: 2) NBS/hv 1) Cly/FeCl3 2) HNO,/H2SO4 1) CH3CH,COCI/AICI 2) H20 оооооооо 3) Zn(Hg)/HCl(aq) 1) SOZ/H,SO 2) Bry/FeBrz 1) (CH3)3CCI/AICI: 2) KMnO/HOIA 2) H30* 1) CH,COCIAICI: 2) H, 3) Bry/FeBry COH 1) SOCI_/pyridine 2) PhCH/AICI 3) H20 1. Br JFeBry 2. Mg/Eto 3. oxirane 4, HO* 1) Bry/FeBry 2) s09/H230 1) NBS/hv 2) PhoNa (1 CH3COCI / AIC وا (2...
Give the missing reagent(s). Matching H2SO., H30 Cl2 1) Br, H;O 2) NaH KMnO Cold, Dilute,Basic...
Give the missing reagent(s). Matching H2SO., H30 Cl2 1) Br, H;O 2) NaH KMnO Cold, Dilute,Basic HCI 1) BH THE 2) H2O2, OH 1) Hg(OAc), H:0 2) NaBH, OH 1) Os 2) (CH3)2S H20, H SO. mCPBA 1) mCPBA 2) H30 Na. 1) OsO. 2) NaHSO; Liquid NH; 1) mCPBA 2) H30, OH Lindlar's Catalyst
1. Give the major product of the following reactions, write NR. if no reaction happens. Indicate the stereochemistr...
1. Give the major product of the following reactions, write NR. if no reaction happens. Indicate the stereochemistry if necessary CHCI KOC(CH3). (CH),COH 1. conc. HBr, heat 2. KOBU, HOBU 1. NaOM, MOH CI 2. BICN 1. 1 eq. BH3. THE 2. H2O2, NaOH, H2O 3. Hg(OAC), MeOH 4. NaBH4, NaOH, H2O 1. conc. HCI 2. LDA, THF 3. O. CH,OH 4.(CH), 1. Hg(OAC), THE 2. NaBH, NaOH, H2O > OH (Hint: product has a bicyclic ring)
3. Predict the product(s) using the same alkene reactant for the following reactions: HB H.O, hv H.0/H,0 1, HE, THI | 0 2. NaBH,/NaOH 1. B.H/THF 2. H.O./NaOH KMnO,H,O cold 1. Oso 2. NaHSO, 1. KMnO,/OH/heat 2. H,0 1. O,CH,CI 2. Zn/H,
3. Predict the product(s) using the same oduct(s) using the same alkens reactant for the following reactions CH,CI, H,0 CI, CH,OH HI DB HBr H.O./hy H,O/H,0 1. Hg.THF-H,0 2. NaBH/NaOH 1. B.H/THF 2. H.O./NaOH KMnO,/H,0 cold 1. Oso 2. NaHSO, 1. KMnO/OH/heat 2. H,0 1. O,/CH,CI, 2. Zn/H,0
4. Predict the product(s) using th using the same skene reactant for the following reactions 10 CH,CI Br CH,OH HI DBE LIB H.Ohv H.O/H,0 1. Hg. THF-H,O 2. NaBH/NaOH 1. B.H/THF 2. H.OX/NaOH KMnO/H,O cold 1. Os 2. NaHSO, 1. KMnO/OH/heat 2. H,0 1. O,/CH,CI, 2. Zn/H,O
2. Predict the product(s) using the same alkene reactant for the following reactions: H,O, hv H5OH,O 1, HE. THI -H0 2. NaBH,/NaOH 1. B H/THF 2. H.O./NaOH KMnO /H,0 cold 1. Oso 2. NaHSO 1. KMnO/OH heat 2. H,0 1. O,/CH,CI, 2. Zn/H,0 1.0, 2. H,O/OH
Predict the product(s) using the same alkene reactant for the following reactions: 2. н, (a) Pt/C D, (b) Pt/C Cl, (c) CH,Cl, Br, (d) Н.о Cl, (e) CH,OH HI (0 DBr (g) НВr (h) нолу ноно (0) 1. Hg". THF-H,O 2. NaBH/NaOH 1. В, Н, ТHF (k) 2. H,O/NaOH кMпо, H,о (I) cold 1. OsO, (m) 2. NaHSO, 1. KMnO/OH/heat (n) 2. Н.О" 1. 0/CH,CI, (o) 2. Zn/H,O 1. O, (p) 2. H.о/он
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
Provide the major product(s) for the following reactions: Show Stereochemistry when necessary (10 points total) Br HBr CH2CI Br2 HBr Но ROOR CH,OH Н,о н* Н,о° 1) Hg(O,CCF3)2 CH,OH 1) BН, THF 2) H,О, NaOH, Нао 2) NaBH, NaOH 1) Hg(OAc) Н0, THF/ Hа Pd/C 2) NaBH, NaOH
1. Provide the major organic product(s) for each of the following reactions: 1) HNOZ/H, SO 2) Sn/HCl(aq) 3) HO 1) (CH3)2CHCI/AICI: 2) NBS/hv 1) Cly/FeCl3 2) HNO,/H2SO4 1) CH3CH,COCI/AICI 2) H20 оооооооо 3) Zn(Hg)/HCl(aq) 1) SOZ/H,SO 2) Bry/FeBrz 1) (CH3)3CCI/AICI: 2) KMnO/HOIA 2) H30* 1) CH,COCIAICI: 2) H, 3) Bry/FeBry COH 1) SOCI_/pyridine 2) PhCH/AICI 3) H20 1. Br JFeBry 2. Mg/Eto 3. oxirane 4, HO* 1) Bry/FeBry 2) s09/H230 1) NBS/hv 2) PhoNa (1 CH3COCI / AIC وا (2...
Give the missing reagent(s). Matching H2SO., H30 Cl2 1) Br, H;O 2) NaH KMnO Cold, Dilute,Basic HCI 1) BH THE 2) H2O2, OH 1) Hg(OAc), H:0 2) NaBH, OH 1) Os 2) (CH3)2S H20, H SO. mCPBA 1) mCPBA 2) H30 Na. 1) OsO. 2) NaHSO; Liquid NH; 1) mCPBA 2) H30, OH Lindlar's Catalyst
1. Give the major product of the following reactions, write NR. if no reaction happens. Indicate the stereochemistry if necessary CHCI KOC(CH3). (CH),COH 1. conc. HBr, heat 2. KOBU, HOBU 1. NaOM, MOH CI 2. BICN 1. 1 eq. BH3. THE 2. H2O2, NaOH, H2O 3. Hg(OAC), MeOH 4. NaBH4, NaOH, H2O 1. conc. HCI 2. LDA, THF 3. O. CH,OH 4.(CH), 1. Hg(OAC), THE 2. NaBH, NaOH, H2O > OH (Hint: product has a bicyclic ring)
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