if i could explanations and help with these! thank you so much! 4. What is(are) the...
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Question 1: Find a table that compares the relative reaction rates (Su2) for alkyi fluorides, chlorides, bromides and iodides (Section 9.2 in the textbook). Which halide is the best leaving group? How much faster is it than the slowest halide leaving group? Question 2: The nature of the solvent plays a big role in determining the type of substitution or elimination mechanism that takes place (SH1, SN2, E1 or E2). Draw structures for 2...
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Student ID# 12. What is the major organic product obtained from the following reaction? o-s CH₂ pyridine NO+ a. b. < d 1 2 3 4 13. What is the major organic product obtained from the following reaction? OH Haso, SH a b. c. d. 1 2 3 4 14. What is the major organic product obtained from the following reaction? CrO; ОН H2SO4 H2O a. l-butene,...
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7. Snl reactions usually proceed with athons a rectn equal amounts of inversion and retention at the center undergoing substitution. slightly more inversion than retention at the center undergoing substitution. ntly more retention then inversion at the center undergoing substitution. (D) (E) sligh complete inversion at the center undergoing substitution. complete retention at the center undergoing substitution How many distinct alkene products are possible when the alkyl bromide below undergoes E2...
4) Can you ever have only SN2 or only SN1?
Introduction Alkyl halides can be prepared from alcohols by reactions with hydrogen halides (HCI, HBr, or HI) via nucleophilic substitution. In this type of reaction, the nucleophile displaces a leaving group from a carbon atom of an organic substrate (here the alcohol once protonated). Both electrons of the new bond to the carbon are provided by the nucleophile while the leaving group departs with both electrons of its bond to...
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What is the name of the product formed from the following Sn1 reaction? When a substitution reaction takes place at a stereocentre, which of the following statements is TRUE? VoH HI Select one: a. An SN2 reaction results in inversion of configuration only b. An SN 1 reaction results in inversion of configuration only c. An SN2 reaction results in racemisation only d. An SN2 reaction results in retention...
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How are the following two compounds related? CH CH3 HO -H HO -Н Given the following substitution reaction, what would the effect be of changing the solvent from CH3OH to (CH3)2S=0? H- OH H OH VS HO -H H -OH H -OH HO H + CH (CH2CH2-Br NaOH CH;(CH2), CH2-OH + NaBr CH OH CH2OH A. The reaction rate will increase. OB. There is no effect on the rate of the reaction, C. The...
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Chem 202, Summer 2020 Homework Packet 5 part 2 (Subt and Elim Reactions) 5. Alcohol Reactions Predict the product(s) OR starting material of the following reactions. Remember, Hydride shifts are possible if/when a more stable carbocation can exist (depending on reaction mechanism)! Put your answers in the indicated boxes (only organic molecules HCI a H20 H2SO4 (cat.) b. + H2O Δ MAJOR product Minor product H,904 (cat.) + H2O HBr d. + H20 OH A MAJOR product Minor...
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What is the best route for converting the alcohol to the ether as shown below using a substitution reaction or a sequence of substitution reactions while preserving the stereochemistry at the chiral center? OH осн. a. LICH b.i. HCl; il CH2OH c. i. HCI; il NaOCH3 d. NaOCH3 CH3OH f. i. PC13: il. NaOCH3
Consider the SN2 reaction of butyl bromide with hydroxide ion , Assuming no other changes, what effect on the reaction rate would result from simultaneously doubling the concentrations of both butyl bromide and hydroxyl ion No effect (B)It would double the rate (C)it would increase the rate six times (D) It would increase the rate four times. 2. Which alky halide would you expect to undergo SN1 hydrolysis most rapidly? (A) (CH3)3C-I (B) (CH3)3C-Br (C) (CH3)3C-Cl (D) (CH3)3C-F 3....
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reaction scheme for the experiment.
Synthesis of an Alkyl Halide: A Nucleophilic Substitution Reaction, Part I Pre-lab Assignment for Synthesis of an Alkyl Halide: A Nucleophilic Substitution Reaction, Part 1 1. From The Organic Chem Lab Survival Manual ( edition) by Zubrick • Review pages 201-204: Standard Reflux. • Review pages 127-140: Extraction • Review pages 164-189: Distillation, Simple Distillation. The Distillation Example, and The Distillation Mistake. 2. Read this...