11. Conformation IV, less crowd compare to I.
12. Option B, II only priority order is in anticlockwise direction hence S configuration
13. Compounds I and V since they have plane of symmetry
14. Option D, Constitutional isomers since position of OH is different in both structures
15. Option A,2 only since it has only one chiral center.
11,12,13,14,15 pls 11) The most stable confermation of 3a a-ca e.caw ca in the back) 12)...
2) Order the following alkenes from most stable to least stable Нас Нас с-сн, н,с Hас +C- Нас н CHs -CH3 H Hе most stable least stable (a) I (b) I (c) I ll (d) 7) Order the following C-H bonds from strongest to weakest. strongest weakest (a) (b) (c) II (d) 8) Which of the following is represents the lowest energy transition state for the addition of BH, to 2-methyl-1-propene? quCH «сHs нСи Нас (b) (a) Нив--н H H...
give explanations pls Chuper Cыper 5 MULTIPLE CHOICE QUESTIONS Part 5: Stereochemistry 5. Pairs of enantiomers are: Answers on page 24-26 Topic: Identifications a nd Comparisons нс Снснснь н,с сHсH,сн, CI снснсн I. Which of the following is the enantiomer of the following substan ce? п Br CH сн ҫH.сH,сн, HC C сна H I II III снснсн, A) IV II and III, IV It does not have a non-superposable enantiomer Both II and III E C) II, IV D)...
Which solvent(s) listed below would be satisfactory in Snl reactions? 0 o Н;С CH; DMSO H3C Н;С CH3CH2OH H DMF I II III a. I only b. II only c. III only d. I and II Oe. I and III f. II and III Og. All of the above What two products are expected in the following reaction? CH3 HBT H H BI CH CH; CH BI H Br I II III H Br Br H CH; CH IV V...
H 9. For each molecule: 1) Identify all possible enantiomers and distinguish those that are enantiomers, diastereomers and meso compounds. II) Assign the absolute configuration of chiral carbons in each molecule OCH3 HO+Br HS+CN H2N-CH3 HOSH Он HO+CH3 н OCH3 Сн, ососна Br +D HOCH HC-BrHN+Br CH 8. For the following compounds, assign the absolute configuration for those with chiral carbons and identify those that are NOT enantiomers HO C-C-OHY -CCIN 13CH3 HAN CH3 CH3 осі H-CH3 H2N+CH H O+COOH...
Which of the following structures is most stable? 2) How many stereoisomers does the molecule below have? (СН), С+ снен снаси сна OH CH₃ br. a) 3 6) 4 c) 6 d) 8 e 9 3) Which of the following molecules below are chiral? 0) to A Boh A MOH HOS DBr e) 1, 2 and 3 a) Only 1 b) 1 and 3 c) 2 and 3 d) 1 and 3 What is the relationship between the following two...
Need help with these Orgo Chem problems. mostly with the naming part. thank you Draw the most stable chair conformation of cis-1,2-dimethylcyclohexane 1) Draw the ring flip of the structure in question #1 2) Draw all contributing resonance structures for the following molecules. Make sure to show all arrows showing 3) movement of electrons. :c: Name the following molecules 4) 5) Assign R/S configuration to the molecule, 2-bromobutane, shown Br H H H HyC CH3 2-bromobutane Which of the following...
1. Which of the following types of isomer differs only by the rotation about single bonds? a. d diastereomers constitutional b. configurational e enantiomers c conformational 2. The Newman projection looking down the indicated bond in the following species is best represented by which of the following (, I, I, IV, or V)? Br HC H. н. CI сн, Br нс HC Br IV I1 а. I b II e.v c. III 3. Which substituents are anti to each other?...
What would be the major product of the following reaction? Br2, ca CH3 CH3 CH3 CH H-LB BH H B BH H-EB BH Br- H H -Br CsHy CHT Cat Cat IV A. Equal amounts of I and II. B. Equal amounts of II and III. OC Equal amounts of III and IV. D. I and Il as major products, III and IV as minor products. E. All of these choices in equal amounts.
ring but no triple bonds 6) What is the product of the following reaction ? 1)2 moles Hc-MgBr осн, 2) Н,он,о н.с он сн Cн, -сн, н.с осн, -сн. Н,с -сн н,с D. 7) Which of the following reactions is correct and occurs as indicated ? CI K,Cr,O7, H,SO4, H,0 H. он он K,Cr,0,, H,SO4, H,0 111 CI PCC, CH,Cl, H. ОН I and II B) I and III C) Il and II D) I, Il and III A)
I only need help with f, g, h, and i. Thank you! 2. Indicate if the following structures are chiral or achiral (remember to look for the internal plane of symmetry) a) (CH3)3CCH(CH3)2 b) CH3CH2CH(CH3)CH2CH3 HO OH Он d) он но. Сно CH3 i)H3C. g) h) Н- Br CH20H н н- -Br НООС С. Н CH2CH3 CH3 H н CI