Problem

Suggest structures for [MBrgj3-, [MC15]2_ and [MBr4]~ (M = Ga or In), (b) In the salt [Et4...

Suggest structures for [MBrgj3-, [MC15]2_ and [MBr4]~ (M = Ga or In), (b) In the salt [Et4N]2[InCl5], the anion has a square-based pyramidal structure, as does [T1C15]2_ in the salt [H3N(CH2)5NH3][T1C15]. Comment on these observations in the light of your answer to part

(a), Suggest methods of preparing [H3N(CH2)5NH3][T1C15] and Cs3[T12C19],


(b) Explain how magnetic data enable you to distinguish between the formulations GaCl2 and Ga[GaCl4| for gallium dichloride.

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Solutions For Problems in Chapter 13