Problem

Primary aliphatic amines (RNH2) react with nitrous acid in the same way that primary aryla...

Primary aliphatic amines (RNH2) react with nitrous acid in the same way that primary arylamines (ArNH2) do, to form diazonium ions. But alkyldiazonium ions RN2 + are much less stable than aryldiazonium ions ArN2 + andreadily lose nitrogen even at 0°C. Explain the difference.

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