Problem

The zinc-air battery shows much promise for electric cars because it is lightweight and re...

The zinc-air battery shows much promise for electric cars because it is lightweight and rechargeable:

The net transformation is ZnO(s). (a) Write the half-reactions at the zinc-air electrodes, and calculate the standard emf of the battery at 25°C. (b) Calculate the emf under actual operating conditions when the partial pressure of oxygen is 0.21 atm. (c) What is the energy density (measured as the energy in kilojoules that can be obtained from 1 kg of the metal) of the zinc electrode? (d) If a current of 2.1 X 105 A is to be drawn from a zinc-air battery system, what volume of air (in liters) would need to be supplied to the battery every second? Assume that the temperature is 25°C and the partial pressure of oxygen is 0.21 atm.

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