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Topical Questions These questions are keyed to the major topics in the chapter. Usually...

Topical Questions

These questions are keyed to the major topics in the chapter. Usually a question that is answered at the back of this book is paired with a similar one that is not.

The Ne atom and the molecules HF, H2O, NH3, and CH4 all have the same number of electrons. In a thought experiment, you can make HF from Ne by removing a single proton a short distance from the nucleus and having the electrons follow the new arrangement of nuclei so as to make a new chemical bond. You can do the same for each of the other molecules. (Of course, none of these thought experiments can actually be done because of the enormous energies required to remove protons from nuclei.) For all of these substances, make a plot of (a) the boiling point in kelvins versus the number of hydrogen atoms and (b) the molar heat of vaporization versus the number of hydrogen atoms. Explain any trend that you see in terms of intermolecular forces.

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