Problem

and ClF6 – are all octahedral, but and IF6 – are distorted, with a lone pair on the...

and ClF6 are all octahedral, but and IF6 are distorted, with a lone pair on the central atom apparently influencing the shape. Suggest a reason for the difference in shape of these two groups of ions. (See J. Pilmé, E. A. Robinson, R. J. Gillespie, Inorg. Chem ., 2006 , 45 , 6198.)

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Solutions For Problems in Chapter 3