The reaction of TeCl4 with PPh3 in THF solution in air leads to the formation of the salt [(Ph3PO)2H]2[Te2CI1o]. Structural data reveal that each Te centre in the anion is in an approximately octahedral environment, (a) Suggest a structure for [Te2Cl1o]2-. (b) The cation [(Ph3PO)2H]H is derived from the phosphine oxide Ph3PO. Suggest a structure for the cation and comment on its bonding.
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