Problem

Suppose that an infinitesimal crystal of ice is added to 10.0 g of supercooled liquid wate...

Suppose that an infinitesimal crystal of ice is added to 10.0 g of supercooled liquid water at − 10.0°C in an adiabatic container and the system reaches equilibrium at a fixed pressure of 1 atm. (a) What is ΔH for the process? (b) The equilibrium state will contain some ice and will therefore consist either of ice plus liquid at 0°C or of ice at or below 0°C. Use the answer to (a) to deduce exactly what is present at equilibrium, (c) Calculate ΔS for the process. (See Prob. 2.49 for data.)

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Solutions For Problems in Chapter 3