Propose structural formulas for the repeating disaccharide unit in these polysaccharides.
(a) Alginic acid, isolated from seaweed, is used as a thickening agent in ice cream and other foods. Alginic acid is a polymer of D-mannuronic acid in the pyranose form joined by ß-1,4-glycosidic bonds.
(b) Pectic acid is the main component of pectin, which is responsible for the formation of jellies from fruits and berries. Pectic acid is a polymer of D-galacturonic acid in the pyranose form joined by α-1,4-glycosidic bonds.
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