Problem

Consider the system at 25°C. At zero time, only A, B, and C are present. The re...

Consider the system

at 25°C. At zero time, only A, B, and C are present. The reaction reaches equilibrium 10 min after the reaction is initiated. Partial pressures of A, B, and D are written as PA, PB, and PD.

Answer the questions below, using LT (for is less than), GT (for is greater than), EQ (for is equal to), or MI (for more information required).

(a) P D at 11 min ________ PD at 12 min.

(b) P A at 5 min ________ PA at 7 min.

(c) K for the forward reaction ________ K for the reverse reaction.

(d) At equilibrium, K ________ Q.

(e) After the system is at equilibrium, more of gas B is added. After the system returns to equilibrium, K before the addition of B ________ K after the addition of B.

(f) The same reaction is initiated, this time with a catalyst. K for the system without a catalyst ________ K for the system with a catalyst.

(g) K for the formation of one mole of D ________ K for the formation of two moles of D.

(h) The temperature of the system is increased to 35°C. PB at equilibrium at 25°C ________ PB at equilibrium at 35°C.

(i) Ten more grams of C are added to the system. PB before the addition of C ________ PB after the addition of C.

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