Diels–Alder reaction of a monosubstituted diene (such as CH2==CH—CH==CHOCH3) with a monosubstituted dienophile (such as CH2==CHCHO) gives a mixture of products, but the 1,2-disubstituted product often predominates. Draw the resonance hybrid for each reactant and use the charge distribution of the hybrids to explain why the 1,2-disubstituted product is the major product.
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