Problem

This table shows the effect of changing ligands on the dissociation rates of CO cis to t...

This table shows the effect of changing ligands on the dissociation rates of CO cis to those ligands. Explain the effect of these ligands on the rates of dissociation. Include the effect of these ligands on Cr – CO bonding and on the transition state, presumed to be square-pyramidal. (See J. D. Atwood, T. L. Brown, J. Am. Chem. Soc ., 1976 , 98 , 3160).

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Solutions For Problems in Chapter 12