Problem

Rationalize the following signal multiplicities in the 119Sn NMR spectra of some halo-anio...

Rationalize the following signal multiplicities in the 119Sn NMR spectra of some halo-anions and, where possible, use the data to distinguish between geometric isomers [iyF 100% I = A]:

(a) [SnCl5F]2- doublet;


(b) [SnCl4F2]- isomer A, triplet; isomer B, triplet;


(c) [SnCl3F3]2- isomer A, doublet of triplets; , 2 isomer B, quartet;


(d) [SnCl2F4] isomer A, quintet; isomer B, triplet  f triplets;


(e) [SnClF5l2 doublet of quintets;


(f) [SnF6]2- septet.

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Solutions For Problems in Chapter 14