Problem

(a) Under certain conditions, the reaction of 0.5 M 1-bromobutane with 1.0 M sodium...

(a) Under certain conditions, the reaction of 0.5 M 1-bromobutane with 1.0 M sodium methoxide forms 1-methoxybutane at a rate of 0.05 mol/L per second. What would be the rate if 0.1 M 1-bromobutane and 2.0 M NaOCH3 were used?

(b) Consider the reaction of 1-bromobutane with a large excess of ammonia (NH3). Draw the reactants, the transition state, and the products. Note that the initial product is the salt of an amine (RNH3+Br-), which is deprotonated by the excess ammonia to give the amine.

(c) Show another SN2 reaction using a different combination of an alkoxide and an alkyl bromide that also produces1-methoxybutane.

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