Problem

Give the structure including stereochemistry of the product of each of the following react...

Give the structure including stereochemistry of the product of each of the following reactions.

(a)


(b)


(c)

Sample Solution (a) Palladium-catalyzed reactions of organozinc compounds with alkenyl halides give cross-coupling in which bond formation occurs between the carbon attached to zinc and the carbon attached to the halogen. The stereochemistry at the double bond of the iodoalkene is retained. The product is (E)-6-methyl-1,5-decadiene.

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Solutions For Problems in Chapter 15