Problem

The table below gives the average composition of the Earth’s atmosphere (ppm = parts per m...

The table below gives the average composition of the Earth’s atmosphere (ppm = parts per million). Water vapour is also present in small and variable amounts.

Gas

Average amount/ppm

Gas

Averageamount/ppm

He

5.2

CH4

1.72

Ne

18

CO

0.12

Ar

9340

CO2

355

Kr

1.1

 N2O

0.31

Xe

0.09

 NO

<0.0

H2

0.58

O3

0.1-0.01

N2

780840

SO2

<10-4

O2

209460

 NH3

<10-3

(a) Draw a Lewis structure for N20, ensuring that each atom obeys the octet rule,


(b) Use the VSEPR model to predict the molecular shapes of SO2, NH3, N2O, CH4 and CO2.


(c) Which of the gases in the table are radicals? For each of the gases you have chosen, explain how the radical nature arises,


(d) O3 (ozone) is only present in <0.1 ppm. Nonetheless, it is a vital component of the Earth’s atmosphere. Why?


(e) Draw an MO diagram for the formation of N2 from two N atoms, using only the valence orbitals. Use the diagram to rationalize why N2 is chemically very inert,


(f) What is the relationship between the monoatomic gases in the Earth’s atmosphere?

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Solutions For Problems in Chapter 2