A triatomic molecule like hydrogen sulfide (H2S) consists of two hydrogen atoms of mass m and one sulfur atom of mass M constrained by atomic bonding forces to assume the triangular configuration shown in Figure. Assume that the bonding forces can be approximated by springs whose force constant is k. When the three atoms are in their equilibrium configuration, the HS distance is a = 1.67 × 10–10 m and the H–S–H vertex angle is approximately 2α = 90°. Find the normal frequencies and normal modes of oscillation. Assume that the hydrogen atoms do not interact directly with each other.
Figure
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