Identify the alkene obtained on dehydration of each of the following alcohols:
(a) 3-Ethyl-3-pentanol
(b) 1-Propanol
(c) 2-Propanol
(d) 2,3,3-Trimethyl-2-butanol
Sample Solution (a) The hydrogen and the hydroxyl are lost from adjacent carbons in the dehydration of 3-ethyl-3-pentanol.
The hydroxyl group is lost from a carbon that bears three equivalent ethyl substituents. β elimination can occur in any one of three equivalent directions to give the same alkene, 3-ethyl-2-pentene.
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