Problem

(a) The lists below show wrongly paired molecules or ions and point groups. Assign the cor...

(a) The lists below show wrongly paired molecules or ions and point groups. Assign the correct point group to each species.

Molecule or ion

Point group

[H30] +

^3h

C2H4

 Dooh

CH2C12

Td

so3

c3v

CBr4

c„v

[icur

 Alb.

HCN

^4h

Br2

c2v


(a)    A molecule X2FIft belongs to the D3d point group. Does the molecule have an eclipsed or a staggered conformation?


(b)   Figure 5.35 shows the lowest energy a]g MO in ethane If the molecule had an eclipsed rather than a staggered conformation, what would be the symmetry label of the corresponding MO?

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Solutions For Problems in Chapter 5