Problem

The second-order rate constant (in units of M−1s−1) for acid-catalyzed hydration at 25 °C...

The second-order rate constant (in units of M−1s−1) for acid-catalyzed hydration at 25 °C is given for each of the following alkenes:

a. Why does (Z)-2-butene react faster than (E)-2-butene?


b. Why does 2-methyl-2-butene react faster than (Z)-2-butene?


c. Why does 2,3-dimethyl-2-butene react faster than 2-methyl-2-butene?

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