Problem

(Membrane reactor) The first-order, reversible reactionis taking place in a membrane react...

(Membrane reactor) The first-order, reversible reaction

is taking place in a membrane reactor. Pure A enters the reactor, and B diffuses through the membrane. Unfortunately, some of the reactant A also diffuses through the membrane.

(a) Plot and analyze the flow rates of A, B, and C down the reactor, as well as the flow rates of A and B through the membrane.


(b) Compare the conversion profiles of a conventional PFR with those of a membrane reactor. What generalizations can you make?


(c) Would the conversion of A be greater or smaller if C were diffusing out instead of B?


(d) Discuss qualitatively how your curves would change if the temperature were increased significantly or decreased significantly for an exothermic reaction. Repeat the discussion for an endothermic reaction.

k = 10 min−1

KC = 0.01 mol2/dm6

kCA = 1 min−1

kCB = 40 minr−1

FA0 =100 mol/min

v0 = 100 dm3/min

Vreactor = 20 dm3

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Solutions For Problems in Chapter 4