Problem

The uncoiling of deoxyribonucleic acid (DNA) is a first-order reaction. Its activation e...

The uncoiling of deoxyribonucleic acid (DNA) is a first-order reaction. Its activation energy is 420 kJ. At 37°C, the rate constant is 4.90 × 104 min1.

(a) What is the half-life of the uncoiling at 37°C (normal body temperature)?

(b) What is the half-life of the uncoiling if the organism has a temperature of 40°C (<104°F)?

(c) By what factor does the rate of uncoiling increase (per °C) over this temperature interval?

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