Cell EMF under Nonstandard Conditions (Section)
The cell in Figure could be used to provide a measure of the pH in the cathode half-cell. Calculate the pH of the cathode half-cell solution if the cell emf at 298 K is measured to be +0.684 V when [Zn2+] = 0.30 M and PH2 = 0.90 atm.
Why do Na+ ions migrate into the cathode half-cell as the cell reaction proceeds?
Figure A voltaic cell using a standard hydrogen electrode (SHE). The anode half-cell is Zn metal in a Zn(NO3)2(aq) solution, and the cathode half-cell is the SHE in a HNO3(aq) solution.
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