The permeability coefficient of a type of small gas molecule in a polymer is dependent on absolute temperature according to the following equation:
where PM0 and Qp are constants for a given gas–polymer pair. Consider the diffusion of hydrogen through a poly(dimethyl siloxane) (PDMSO) sheet 20 mm thick. The hydrogen pressures at the two faces are 10 and 1 kPa, which are maintained constant. Compute the diffusion flux [in (cm3 STP)/cm2 s] at 350 K. For this diffusion system
PM0 = 1.45 × 10−8 (cm3 STP) (cm)/(cm2 s Pa)
Qp = 13.7 kJ/mol
Assume a condition of steady-state diffusion.
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