Problem

A simple two-component solution is one for whichΔmixG = nART ln xA + nBRT ln xB + (nA + nB...

A simple two-component solution is one for which

ΔmixG = nART ln xA + nBRT ln xB + (nA + nB)xAxBW(T, P)

at constant T and P, where W(T, P) is a function of T and P. Statistical mechanics indicates that when the A and B molecules are approximately spherical and have similar sizes, the solution will be approximately simple. For a simple solution, (a) find expressions for ΔmixH, ΔmixS, and ΔmixV;(b) show that with a similar equation for μB; (c) find expressions for the vapor partial pressures PA and PB, assuming ideal vapor.

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Solutions For Problems in Chapter 9